☣️ UN 3283 • CLASS 6

UN 3283 — Selenium compound, solid, n.o.s.

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3283 is Selenium compound, solid, n.o.s., a broad toxic selenium solid entry assigned to ERG Guide 151. Dust and selenium-contaminated runoff are key concerns.

Hazard overview: TOXIC selenium compound solid, n.o.s.; inhalation of dust, ingestion or skin contact may cause severe injury. Dust can contaminate clothing, tools, soil and runoff. Combustibility varies; heating or fire may produce toxic selenium oxide fumes.

Response guidance: For UN 3283, isolate the area, avoid exposure and use SCBA where vapor, dust, smoke or fire is present. Verify exact controls with SDS and ERG 151.

Firefighter training notes: Training for UN 3283 should emphasize product verification, SCBA use, vapor/dust monitoring, fire behavior, decontamination and runoff control. Use ERG 151, SDS and local SOP.

Regulatory context: Selenium compound, solid, n.o.s. is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, composition, concentration and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Selenium compound, solid, n.o.s. should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

Advertisement

UN 3283 Quick Details

UN 3283
Product name: Selenium compound, solid, n.o.s.
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate spill area at least 25 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider evacuation

Common Hazards of UN 3283

  • TOXIC selenium compound solid, n.o.s.; inhalation of dust, ingestion or skin contact may cause severe injury.
  • Dust can contaminate clothing, tools, soil and runoff.
  • Combustibility varies; heating or fire may produce toxic selenium oxide fumes.
  • Some selenium compounds may be soluble or environmentally persistent.
  • Runoff may carry toxic selenium contamination and harm waterways.
  • Avoid dust generation and all unprotected contact.
  • Exact selenium compound and solubility must be verified from SDS.

Chemical Identity & Physical Properties

Varies by specific compound; typically gray to black or reddish powders or crystalline solids at room temperature. May be odorless or have slight odor depending on compound.

Also known asSelenium compoundsOrganoselenium compoundsSelenium derivativesSelenium salts
AppearanceVaries by specific compound; typically gray to black or reddish powders or crystalline solids at room temperature. May be odorless or have slight odor depending on compound.
Flash PointNot applicable (non-flammable solid, though may burn in fire)
Boiling PointNot applicable (decomposes or sublimes at elevated temperatures)
Vapor DensityNot applicable (solid)
Water ReactivityGenerally stable with water, though some selenium compounds may hydrolyze slowly in moisture
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3283

Extinguishing Media

Use agents compatible with the exact product and SDS; cool containers from protection and contain toxic runoff.

PPE Requirements

⚠️ Level B minimum; SCBA required in fire or confined spaces; chemical-resistant gloves and full body protection mandatory; avoid all skin contact due to high toxicity

Use positive-pressure SCBA for vapor, dust, mist, smoke or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 151: isolate spill area at least 25 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 3283 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated liquid, dust, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 151, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
Advertisement

📋 Copy & Share Field Card

UN 3283 — Selenium compound, solid, n.o.s.
HAZMAT RADIO NOTE — UN 3283 Product: Selenium compound, solid, n.o.s. Class 6 / Toxic / ERG 151 PPE: Level B minimum; SCBA required in fire or confined spaces; chemical-resistant gloves and full body protection mandatory; avoid all skin contact due to high toxicity ISOLATION: ERG 151: isolate spill area at least 25 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3283 — Selenium compound, solid, n.o.s. Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Varies by specific compound; typically gray to black or reddish powders or crystalline solids at room temperature. May be odorless or have slight odor depending on compound. Water Reactivity: Generally stable with water, though some selenium compounds may hydrolyze slowly in moisture Extinguishing: Use agents compatible with the exact product and SDS; cool containers from protection and contain toxic runoff. PPE: Level B minimum; SCBA required in fire or confined spaces; chemical-resistant gloves and full body protection mandatory; avoid all skin contact due to high toxicity Isolation: ERG 151: isolate spill area at least 25 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider evacuation — Key Hazards — • TOXIC selenium compound solid, n.o.s.; inhalation of dust, ingestion or skin contact may cause severe injury. • Dust can contaminate clothing, tools, soil and runoff. • Combustibility varies; heating or fire may produce toxic selenium oxide fumes. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/selenium-compound-solid-n-un-3283 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3283 Selenium compound, solid, n.o.s. Cls6 ERG151 | allfirefighter.com/hazmat/un/selenium-compound-solid-n-un-3283SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/selenium-compound-solid-n-un-3283

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 3283

UN 3283 is Selenium compound, solid, n.o.s., assigned to ERG Guide 151.

Flammability depends on the exact substance; toxic/corrosive exposure and decomposition products are the main concerns.

TOXIC selenium compound solid, n.o.s.; inhalation of dust, ingestion or skin contact may cause severe injury. Dust can contaminate clothing, tools, soil and runoff. Combustibility varies; heating or fire may produce toxic selenium oxide fumes.

Use positive-pressure SCBA for vapor, dust, mist, smoke or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use agents compatible with the exact product and SDS; cool containers from protection and contain toxic runoff.

This broad entry can cover different chemicals, so toxicity, flammability, reactivity and PPE can change.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.