☣️ UN 3383 • CLASS 6
Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A)
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 3383
Class: 6
Placard type: Toxic
ERG: Guide 131 (check current ERG)
Isolation: ERG 131: Isolate spill 100m all directions; initial evacuation 300m downwind daytime, 800m downwind nighttime; if tank/rail car involved in fire, isolate 1600m all directions
Chemical & Response Details
| Also known as | Toxic inhalation hazard liquidPIH liquid Zone AFlammable poisonous liquid n.o.s.TIH liquid flammable |
| Appearance | Generic classification for various toxic, flammable liquids with severe inhalation hazards. Physical properties vary by specific chemical; typically liquids at room temperature with vapors that are highly toxic when inhaled. |
| Flash Point | Below 23C (73F) - flammable liquid classification |
| Boiling Point | Varies by specific chemical - refer to SDS for actual substance |
| Vapor Density | Typically heavier than air - vapors stay low and travel |
| Water Reactivity | Varies by specific chemical - some may react, others inert with water |
| Extinguishing | Alcohol-resistant foam, dry chemical, CO2 - avoid water spray on liquid surface |
| PPE | ⚠️ Level A required - SCBA with fully encapsulating chemical protective suit; severe inhalation hazard Zone A demands maximum respiratory protection |
| Isolation | ERG 131: Isolate spill 100m all directions; initial evacuation 300m downwind daytime, 800m downwind nighttime; if tank/rail car involved in fire, isolate 1600m all directions |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
- Inhalation or contact with some of these materials will irritate or burn skin and eyes.
- Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
- Fire will produce irritating, corrosive and/or toxic gases.
- Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas.
- Runoff from fire control or dilution water may cause environmental contamination.
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 3383 — Poisonous by inhalation liquid, flammabl HAZMAT RADIO NOTE — UN 3383
Product: Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A)
Class 6 / Toxic / ERG 131
PPE: Level A required - SCBA with fully encapsulating chemical protective suit; severe inhalation hazard Zone A demands maximum respiratory protection
ISOLATION: ERG 131: Isolate spill 100m all directions; initial evacuation 300m downwind daytime, 800m downwind nighttime; if tank/rail car involved in fire, isolate 1600m all directions
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3383 — Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A)
Class: 6 | Placard: Toxic | ERG Guide: 131
Appearance: Generic classification for various toxic, flammable liquids with severe inhalation hazards. Physical properties vary by specific chemical; typically liquids at room temperature with vapors that are highly toxic when inhaled.
Water Reactivity: Varies by specific chemical - some may react, others inert with water
Extinguishing: Alcohol-resistant foam, dry chemical, CO2 - avoid water spray on liquid surface
PPE: Level A required - SCBA with fully encapsulating chemical protective suit; severe inhalation hazard Zone A demands maximum respiratory protection
Isolation: ERG 131: Isolate spill 100m all directions; initial evacuation 300m downwind daytime, 800m downwind nighttime; if tank/rail car involved in fire, isolate 1600m all directions
— Key Hazards —
• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
• Inhalation or contact with some of these materials will irritate or burn skin and eyes.
• Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/3383 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3383 Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) Cls6 ERG131 | allfirefighter.com/hazmat/un/3383SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3383
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FAQ
TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas. Runoff from fire control or dilution water may cause environmental contamination. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A required - SCBA with fully encapsulating chemical protective suit; severe inhalation hazard Zone A demands maximum respiratory protection
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 131 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.