☣️ UN 3452 • CLASS 6
UN 3452 — Xylidines, solid
Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 3452 Quick Details
UN 3452
Product name: Xylidines, solid
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car involved in fire, isolate 800m in all directions and consider evacuation for 800m.
Common Hazards of UN 3452
- TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
- Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears).
- Contact with molten substance may cause severe burns to skin and eyes.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Combustible material: may burn but does not ignite readily.
- When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion
Chemical Identity & Physical Properties
| Also known as | DimethylanilineDimethylbenzeneamineAminoxyleneMixed xylidinesMethyltoluidines |
| Appearance | White to yellowish-brown crystalline solid at room temperature. Sweet, aromatic amine odor. May darken upon exposure to air and light. |
| Flash Point | 97C (207F) |
| Boiling Point | 213-226C (415-439F) depending on isomer |
| Vapor Density | 4.2 (heavier than air) |
| Water Reactivity | No significant reaction with water. Slightly soluble in water. |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 3452
Extinguishing Media
Alcohol-resistant foam, dry chemical, CO2. Water spray may be used to keep containers cool.
PPE Requirements
⚠️ Level B minimum required. Full chemical protective suit with SCBA for spills or fire. Prevent skin and eye contact as material is absorbed through skin.
Isolation & Evacuation
ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car involved in fire, isolate 800m in all directions and consider evacuation for 800m.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).
First Actions for a UN 3452 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 3452 — Xylidines, solidHAZMAT RADIO NOTE — UN 3452
Product: Xylidines, solid
Class 6 / Toxic / ERG 153
PPE: Level B minimum required. Full chemical protective suit with SCBA for spills or fire. Prevent skin and eye contact as material is absorbed through skin.
ISOLATION: ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car involved in fire, isolate 800m in all directions and consider evacuation for 800m.
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3452 — Xylidines, solid
Class: 6 | Placard: Toxic | ERG Guide: 153
Appearance: White to yellowish-brown crystalline solid at room temperature. Sweet, aromatic amine odor. May darken upon exposure to air and light.
Water Reactivity: No significant reaction with water. Slightly soluble in water.
Extinguishing: Alcohol-resistant foam, dry chemical, CO2. Water spray may be used to keep containers cool.
PPE: Level B minimum required. Full chemical protective suit with SCBA for spills or fire. Prevent skin and eye contact as material is absorbed through skin.
Isolation: ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car involved in fire, isolate 800m in all directions and consider evacuation for 800m.
— Key Hazards —
• TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
• Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears).
• Contact with molten substance may cause severe burns to skin and eyes.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/3452 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3452 Xylidines, solid Cls6 ERG153 | ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car in | allfirefighter.com/hazmat/un/3452SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/3452
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Frequently Asked Questions about UN 3452
TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears). Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum required. Full chemical protective suit with SCBA for spills or fire. Prevent skin and eye contact as material is absorbed through skin.
Water reactivity: No significant reaction with water. Slightly soluble in water.. Recommended extinguishing: Alcohol-resistant foam, dry chemical, CO2. Water spray may be used to keep containers cool..
ERG Guide 153 recommendation: ERG 153: Isolate spill area immediate 50m in all directions. If tank/rail car involved in fire, isolate 800m in all directions and consider evacuation for 800m.
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 153 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.