☣️ UN 2002 • CLASS 4

UN 2002 — Celluloid, scrap

Placard: Spontaneously Combustible. ERG Guide 135. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2002 is Celluloid, scrap, a flammable celluloid scrap entry assigned to ERG Guide 135. Scrap pieces can ignite readily and support rapid flame spread.

Hazard overview: FLAMMABLE celluloid scrap; small pieces and scrap can ignite readily and burn rapidly. Scrap piles may intensify fire and allow rapid flame spread. Heating can release flammable vapors and irritating/toxic decomposition gases.

Response guidance: For a UN 2002 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 135. Establish incident command, isolate the area, stay upwind, control ignition or downwind hazards, cool exposed containers from a protected distance when appropriate and base entry decisions on monitoring and local SOP.

Firefighter training notes: Training for UN 2002 should emphasize fire behavior, exposure routes, air monitoring, PPE selection, evacuation, runoff control and ERG/SDS verification. Use ERG 135, SDS and local SOP.

Regulatory context: Celluloid, scrap is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting and waste handling requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Celluloid, scrap should be stored in a cool, dry, ventilated area away from heat, sparks, flames, oxidizers and incompatible materials. Limit accumulation and protect from friction, impact and dust generation where applicable.

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UN 2002 Quick Details

UN 2002
Product name: Celluloid, scrap
DOT Class: 4
Placard type: Spontaneously Combustible
ERG Guide: 135 (check current ERG)
Initial isolation: ERG 135: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions

Common Hazards of UN 2002

  • FLAMMABLE celluloid scrap; small pieces and scrap can ignite readily and burn rapidly.
  • Scrap piles may intensify fire and allow rapid flame spread.
  • Heating can release flammable vapors and irritating/toxic decomposition gases.
  • May re-ignite after apparent extinguishment if deep-seated heat remains.
  • Friction, impact, heat or contamination can increase ignition risk.
  • Fire may produce nitrogen oxides, carbon monoxide and dense smoke.
  • Runoff may carry plastic and combustion residues.

Chemical Identity & Physical Properties

Solid material, typically appearing as colorless to pale yellow or amber pieces, chips, or fragments. May have a characteristic camphor-like odor. Highly flammable plastic-like material.

Also known asCellulose nitrate scrapNitrocellulose scrapPyroxylin scrapCelluloid waste
AppearanceSolid material, typically appearing as colorless to pale yellow or amber pieces, chips, or fragments. May have a characteristic camphor-like odor. Highly flammable plastic-like material.
Flash PointNot applicable (spontaneously flammable solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityMay ignite on contact with moisture or moist air; water may increase reactivity and ignition risk
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2002

Extinguishing Media

Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition.

PPE Requirements

⚠️ Level B minimum with SCBA; full protective clothing required; material can ignite spontaneously

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.

Isolation & Evacuation

ERG 135: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 135).

First Actions for a UN 2002 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact.
  • Avoid friction, sparks, heat and dust generation; watch for rapid burning or re-ignition.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the release or spill area and expand the perimeter for fire involvement, vapor accumulation, cylinder/tank heating or unknown product identity.
  • Use ERG Guide 135, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2002 — Celluloid, scrap
HAZMAT RADIO NOTE — UN 2002 Product: Celluloid, scrap Class 4 / Spontaneously Combustible / ERG 135 PPE: Level B minimum with SCBA; full protective clothing required; material can ignite spontaneously ISOLATION: ERG 135: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2002 — Celluloid, scrap Class: 4 | Placard: Spontaneously Combustible | ERG Guide: 135 Appearance: Solid material, typically appearing as colorless to pale yellow or amber pieces, chips, or fragments. May have a characteristic camphor-like odor. Highly flammable plastic-like material. Water Reactivity: May ignite on contact with moisture or moist air; water may increase reactivity and ignition risk Extinguishing: Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition. PPE: Level B minimum with SCBA; full protective clothing required; material can ignite spontaneously Isolation: ERG 135: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions — Key Hazards — • FLAMMABLE celluloid scrap; small pieces and scrap can ignite readily and burn rapidly. • Scrap piles may intensify fire and allow rapid flame spread. • Heating can release flammable vapors and irritating/toxic decomposition gases. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/celluloid-scrap-un-2002 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2002 Celluloid, scrap Cls4 ERG135 | allfirefighter.com/hazmat/un/celluloid-scrap-un-2002SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/celluloid-scrap-un-2002

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2002

UN 2002 is Celluloid, scrap, a hazardous material assigned to ERG Guide 135.

Yes. Celluloid scrap is flammable and can burn rapidly, especially in piles.

ERG Guide 135 applies to UN 2002 for initial isolation, protective actions and first response guidance.

FLAMMABLE celluloid scrap; small pieces and scrap can ignite readily and burn rapidly. Scrap piles may intensify fire and allow rapid flame spread. Heating can release flammable vapors and irritating/toxic decomposition gases.

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.

Hot celluloid or scrap piles can retain heat after visible flames are out, so overhaul and monitoring are important.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.