☣️ UN 1695 • CLASS 6

UN 1695 — Chloroacetone, stabilized

Placard: Toxic. ERG Guide 131. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1695 At a Glance

UN 1695 (Chloroacetone, stabilized) is listed as DOT Class 6 Toxic and is assigned to ERG Guide 131. Use this page to review placard data, common hazards, PPE notes, isolation context, first actions, and related UN numbers.

UN 1695 is Chloroacetone, stabilized, a flammable toxic lachrymator liquid assigned to ERG Guide 131. It combines vapor fire risk with severe eye and respiratory irritation.

Hazard overview: UN 1695 presents flammable vapor, flashback, toxic exposure and lachrymator hazards. Vapors can travel to ignition sources, and fire may produce corrosive toxic gases.

Response guidance: For a UN 1695 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 131. Establish incident command, isolate the area, stay upwind, prevent dust, vapor or aerosol exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1695 should emphasize toxic exposure routes, air monitoring, PPE selection, decontamination and preventing contaminated runoff. Use ERG 131, SDS and local SOP.

Regulatory context: Chloroacetone, stabilized is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Chloroacetone, stabilized should be stored in tightly closed compatible containers in a secure toxic-material area according to SDS and local hazardous materials procedures.

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UN 1695 Quick Details

UN 1695
Product name: Chloroacetone, stabilized
DOT Class: 6
Placard type: Toxic
ERG Guide: 131 (check current ERG)
Initial isolation: ERG 131: isolate 25m minimum; for large spill isolate 50m, consider 300m downwind evacuation

Common Hazards of UN 1695

  • FLAMMABLE and toxic lachrymator liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors can cause severe eye tearing, respiratory irritation and skin injury.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Water contact may slowly decompose the material and spread contaminated runoff.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Containers may rupture or explode when heated.
  • Runoff may carry toxic and irritating contamination.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a pungent, irritating odor. Lachrymator (tear-producing agent) at room temperature.

Also known asChloroacetoneChloropropanone1-Chloro-2-propanoneMonochloroacetoneAcetonyl chloride
CAS Number78-95-5
AppearanceColorless to pale yellow liquid with a pungent, irritating odor. Lachrymator (tear-producing agent) at room temperature.
Flash Point40°C (104°F)
Boiling Point119°C (246°F)
Vapor Density3.2 (heavier than air)
Water ReactivitySlowly decomposes in water; avoid prolonged water contact
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1695

Extinguishing Media

Use alcohol-resistant foam, dry chemical or CO2 for fire control when compatible. Water spray may cool containers from a protected position, but direct water streams may spread contaminated liquid.

PPE Requirements

⚠️ Level A or B required; SCBA mandatory; full chemical-resistant suit; severe skin/eye hazard

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because lachrymator effects and skin contact can be severe.

Isolation & Evacuation

ERG 131: isolate 25m minimum; for large spill isolate 50m, consider 300m downwind evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 131).

First Actions for a UN 1695 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist, aerosol or smoke and avoid all skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors out of drains, sewers and low areas.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated liquid, powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, aerosol, fire involvement or unknown concentration is present.
  • Use ERG Guide 131, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1695 — Chloroacetone, stabilized
HAZMAT RADIO NOTE — UN 1695 Product: Chloroacetone, stabilized Class 6 / Toxic / ERG 131 PPE: Level A or B required; SCBA mandatory; full chemical-resistant suit; severe skin/eye hazard ISOLATION: ERG 131: isolate 25m minimum; for large spill isolate 50m, consider 300m downwind evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1695 — Chloroacetone, stabilized Class: 6 | Placard: Toxic | ERG Guide: 131 Appearance: Colorless to pale yellow liquid with a pungent, irritating odor. Lachrymator (tear-producing agent) at room temperature. Water Reactivity: Slowly decomposes in water; avoid prolonged water contact Extinguishing: Use alcohol-resistant foam, dry chemical or CO2 for fire control when compatible. Water spray may cool containers from a protected position, but direct water streams may spread contaminated liquid. PPE: Level A or B required; SCBA mandatory; full chemical-resistant suit; severe skin/eye hazard Isolation: ERG 131: isolate 25m minimum; for large spill isolate 50m, consider 300m downwind evacuation — Key Hazards — • FLAMMABLE and toxic lachrymator liquid; vapors may ignite and form explosive mixtures with air. • Vapors can cause severe eye tearing, respiratory irritation and skin injury. • Vapors are heavier than air and may travel to ignition sources and flash back. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist, aerosol or smoke and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/chloroacetone-stabilized-un-1695 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1695 Chloroacetone, stabilized Cls6 ERG131 | allfirefighter.com/hazmat/un/chloroacetone-stabilized-un-1695SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/chloroacetone-stabilized-un-1695

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1695

UN 1695 is Chloroacetone, stabilized, a hazardous material assigned to ERG Guide 131.

Yes. It is flammable, with vapors that may form explosive mixtures with air.

ERG Guide 131 applies to UN 1695 for initial isolation, protective actions and first response guidance.

UN 1695 presents flammable vapor, flashback, toxic exposure and lachrymator hazards. Vapors can travel to ignition sources, and fire may produce corrosive toxic gases.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because lachrymator effects and skin contact can be severe.

Heavy vapors can collect in drains, sewers, basements or trenches, increasing irritation, toxic exposure and fire risk where applicable.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.