☣️ UN 0072 • CLASS 1

UN 0072 — Cyclonite; RDX; Hexogen, wetted

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0072, known as RDX or Hexogen wetted, is a powerful military and commercial explosive shipped in a water- or alcohol-wetted state to reduce its sensitivity to accidental detonation. The wetting agent acts as a desensitizer, but if the material dries out, it becomes extremely sensitive to heat, shock, and friction.

Hazard overview: UN 0072 presents a mass explosion hazard, meaning the entire load can detonate simultaneously, producing catastrophic blast overpressure and high-velocity fragmentation. Even in its wetted state, RDX remains sensitive to ignition sources, and any fire involvement must be treated as an imminent detonation risk.

Response guidance: Per ERG Guide 112, responders must isolate a minimum of 500 meters (1,600 ft) in all directions and evacuate at least 1,600 meters (1 mile) downwind if the material is involved in fire. Immediate withdrawal is required upon any sign of fire exposure, as no intervention can be safely conducted once detonation risk is elevated.

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UN 0072 Quick Details

UN 0072
Product name: Cyclonite; RDX; Hexogen, wetted
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m (1600 ft) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; consider initial evacuation for 800m in all directions

Common Hazards of UN 0072

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0072 is a white, odorless crystalline solid that is shipped wetted with water or alcohol to stabilize it during transport, but becomes an extremely hazardous dry explosive if the desensitizing agent evaporates.

Also known asRDXHexogenCyclotrimethylenetrinitramineT41,3,5-Trinitro-1,3,5-triazacyclohexaneHexahydro-1,3,5-trinitro-1,3,5-triazine
CAS Number121-82-4
AppearanceWhite crystalline solid, odorless. Shipped wetted with water or alcohol to reduce sensitivity. Stable when properly desensitized but extremely hazardous when dry.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively at approximately 230C/446F)
Vapor DensityNot applicable (solid)
Water ReactivityNo reaction with water; wetting agent used as desensitizer
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0072

Extinguishing Media

Do not use foam or water streams on dry material; may use water fog from distance to keep wetted explosive cool during fire

PPE Requirements

⚠️ Maximum distance and protective cover required; structural firefighters' protective clothing provides NO protection; withdraw immediately if exposed to fire

Maximum protective distance and structural cover are required near UN 0072, as standard structural firefighters' protective clothing provides no meaningful protection against explosive blast or fragmentation.

Isolation & Evacuation

ERG 112: isolate 500m (1600 ft) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; consider initial evacuation for 800m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0072 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0072 — Cyclonite; RDX; Hexogen, wetted
HAZMAT RADIO NOTE — UN 0072 Product: Cyclonite; RDX; Hexogen, wetted Class 1 / Explosive 1.1D / ERG 112 PPE: Maximum distance and protective cover required; structural firefighters' protective clothing provides NO protection; withdraw immediately if exposed to fire ISOLATION: ERG 112: isolate 500m (1600 ft) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; consider initial evacuation for 800m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0072 — Cyclonite; RDX; Hexogen, wetted Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White crystalline solid, odorless. Shipped wetted with water or alcohol to reduce sensitivity. Stable when properly desensitized but extremely hazardous when dry. Water Reactivity: No reaction with water; wetting agent used as desensitizer Extinguishing: Do not use foam or water streams on dry material; may use water fog from distance to keep wetted explosive cool during fire PPE: Maximum distance and protective cover required; structural firefighters' protective clothing provides NO protection; withdraw immediately if exposed to fire Isolation: ERG 112: isolate 500m (1600 ft) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; consider initial evacuation for 800m in all directions — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/cyclonite-rdx-hexogen-wetted-un-0072 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0072 Cyclonite; RDX; Hexogen, wetted Cls1 ERG112 | allfirefighter.com/hazmat/un/cyclonite-rdx-hexogen-wetted-un-0072SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/cyclonite-rdx-hexogen-wetted-un-0072

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0072

Yes, UN 0072 (RDX wetted) is classified as a Division 1.1D explosive, meaning the entire quantity can detonate simultaneously and produce a catastrophic mass explosion.

Because structural firefighting gear offers no protection against explosive blast or fragmentation, responders must maximize distance and use substantial structural cover rather than approaching the material.

ERG Guide 112 directs an isolation distance of 500 meters in all directions and a downwind evacuation of at least 1,600 meters (1 mile) when UN 0072 is involved in fire.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.