☣️ UN 2248 • CLASS 8

UN 2248 — Di-n-butylamine

Placard: Corrosive. ERG Guide 132. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2248 is Di-n-butylamine, a flammable corrosive amine assigned to ERG Guide 132. It combines vapor fire risk with alkaline/corrosive burn hazards.

Hazard overview: FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. Liquid and vapor can burn eyes, skin and respiratory tissue. Vapors are heavier than air and may travel to ignition sources and flash back.

Response guidance: For a UN 2248 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 132. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2248 should emphasize vapor travel, sewer flashback, foam selection, container cooling, ignition control and runoff containment. Use ERG 132, SDS and local SOP.

Regulatory context: Di-n-butylamine is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Di-n-butylamine should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

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UN 2248 Quick Details

UN 2248
Product name: Di-n-butylamine
DOT Class: 8
Placard type: Corrosive
ERG Guide: 132 (check current ERG)
Initial isolation: ERG 132: isolate spill 50m all directions; for large spill isolate 100m, evacuate 500m downwind if fire

Common Hazards of UN 2248

  • FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air.
  • Liquid and vapor can burn eyes, skin and respiratory tissue.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Mixing with water may generate heat and spread alkaline/corrosive contamination.
  • Fire may produce nitrogen oxides and irritating/toxic smoke.
  • Runoff to sewers may create fire, explosion and corrosive contamination hazards.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a fishy, ammonia-like odor. Highly flammable with irritating vapors.

Also known asDibutylamineN-butyl-1-butanamineDBAN,N-dibutylamine
CAS Number111-92-2
AppearanceColorless to pale yellow liquid with a fishy, ammonia-like odor. Highly flammable with irritating vapors.
Flash Point47C (117F)
Boiling Point159C (318F)
Vapor Density4.5 (heavier than air)
Water ReactivitySlightly soluble in water; may release heat on contact but no violent reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2248

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

PPE Requirements

⚠️ Level B minimum; SCBA required; chemical-resistant suit and gloves due to corrosive nature

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 132: isolate spill 50m all directions; for large spill isolate 100m, evacuate 500m downwind if fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 132).

First Actions for a UN 2248 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
  • Use ERG Guide 132, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2248 — Di-n-butylamine
HAZMAT RADIO NOTE — UN 2248 Product: Di-n-butylamine Class 8 / Corrosive / ERG 132 PPE: Level B minimum; SCBA required; chemical-resistant suit and gloves due to corrosive nature ISOLATION: ERG 132: isolate spill 50m all directions; for large spill isolate 100m, evacuate 500m downwind if fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2248 — Di-n-butylamine Class: 8 | Placard: Corrosive | ERG Guide: 132 Appearance: Colorless to pale yellow liquid with a fishy, ammonia-like odor. Highly flammable with irritating vapors. Water Reactivity: Slightly soluble in water; may release heat on contact but no violent reaction Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid. PPE: Level B minimum; SCBA required; chemical-resistant suit and gloves due to corrosive nature Isolation: ERG 132: isolate spill 50m all directions; for large spill isolate 100m, evacuate 500m downwind if fire — Key Hazards — • FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. • Liquid and vapor can burn eyes, skin and respiratory tissue. • Vapors are heavier than air and may travel to ignition sources and flash back. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/di-n-butylamine-un-2248 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2248 Di-n-butylamine Cls8 ERG132 | allfirefighter.com/hazmat/un/di-n-butylamine-un-2248SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/di-n-butylamine-un-2248

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2248

UN 2248 is Di-n-butylamine, a hazardous material assigned to ERG Guide 132.

Yes. It is flammable and corrosive; vapors may form explosive mixtures with air.

ERG Guide 132 applies to UN 2248 for initial isolation, protective actions and first response guidance.

FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. Liquid and vapor can burn eyes, skin and respiratory tissue. Vapors are heavier than air and may travel to ignition sources and flash back.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.