☣️ UN 2490 • CLASS 6

UN 2490 — Dichloroisopropyl ether

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2490 is Dichloroisopropyl ether, a toxic chlorinated ether assigned to ERG Guide 153. Dense liquid spread and toxic chlorinated fire products are key hazards.

Hazard overview: TOXIC chlorinated ether liquid; inhalation, ingestion or skin contact may cause severe injury. Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures and collect in low or confined areas.

Response guidance: For UN 2490, isolate the area, avoid skin contact and use SCBA where vapor, dust, mist or fire is present. Contain toxic/corrosive runoff and verify product controls with SDS and ERG 153.

Firefighter training notes: Training for UN 2490 should emphasize toxic/corrosive exposure routes, skin absorption, SCBA use, decontamination, runoff containment and SDS verification. Use ERG 153, SDS and local SOP.

Regulatory context: Dichloroisopropyl ether is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Dichloroisopropyl ether should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

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UN 2490 Quick Details

UN 2490
Product name: Dichloroisopropyl ether
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation for 800m

Common Hazards of UN 2490

  • TOXIC chlorinated ether liquid; inhalation, ingestion or skin contact may cause severe injury.
  • Combustible material: may burn but does not ignite readily.
  • When heated, vapors may form explosive mixtures and collect in low or confined areas.
  • Liquid is denser than water and may sink, spreading contamination below the surface.
  • Fire may produce hydrogen chloride, phosgene-type gases and other toxic/corrosive smoke.
  • Runoff may carry persistent toxic chlorinated contamination.
  • Avoid all skin contact and contaminated clothing exposure.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a strong, fruity or chloroform-like odor. Denser than water and may sink.

Also known asBis(2-chloroisopropyl) ether2,2'-Dichlorodiisopropyl etherBis(2-chloro-1-methylethyl) etherDCIPDichloroisopropyl ether
CAS Number108-60-1
AppearanceColorless to pale yellow liquid with a strong, fruity or chloroform-like odor. Denser than water and may sink.
Flash Point85C (185F)
Boiling Point187C (369F)
Vapor Density6.0 (heavier than air)
Water ReactivityNo significant reaction with water; slightly soluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2490

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination.

PPE Requirements

⚠️ Level B minimum; SCBA required; chemical-resistant gloves and suit; avoid all skin contact due to toxic absorption risk

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 153: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation for 800m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2490 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated dust, liquid, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 153, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2490 — Dichloroisopropyl ether
HAZMAT RADIO NOTE — UN 2490 Product: Dichloroisopropyl ether Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit; avoid all skin contact due to toxic absorption risk ISOLATION: ERG 153: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation for 800m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2490 — Dichloroisopropyl ether Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Colorless to pale yellow liquid with a strong, fruity or chloroform-like odor. Denser than water and may sink. Water Reactivity: No significant reaction with water; slightly soluble Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination. PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit; avoid all skin contact due to toxic absorption risk Isolation: ERG 153: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation for 800m — Key Hazards — • TOXIC chlorinated ether liquid; inhalation, ingestion or skin contact may cause severe injury. • Combustible material: may burn but does not ignite readily. • When heated, vapors may form explosive mixtures and collect in low or confined areas. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/dichloroisopropyl-ether-un-2490 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2490 Dichloroisopropyl ether Cls6 ERG153 | allfirefighter.com/hazmat/un/dichloroisopropyl-ether-un-2490SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/dichloroisopropyl-ether-un-2490

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2490

UN 2490 is Dichloroisopropyl ether, assigned to ERG Guide 153.

It is combustible but does not ignite readily; toxic/corrosive exposure is the main hazard.

TOXIC chlorinated ether liquid; inhalation, ingestion or skin contact may cause severe injury. Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures and collect in low or confined areas.

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination.

Toxic or corrosive material can contaminate clothing, tools and runoff, extending exposure beyond the original spill area.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.