☣️ UN 2565 • CLASS 8

UN 2565 — Dicyclohexylamine

Placard: Corrosive. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Dicyclohexylamine is a corrosive amine liquid shipped as UN 2565. It can burn when heated and can cause serious injury through vapor, mist or direct contact.

Hazard overview: Dicyclohexylamine can cause severe skin and eye burns and respiratory irritation. Fire can produce toxic nitrogen oxide fumes, and spill runoff may be alkaline and corrosive.

Response guidance: Isolate the spill, prevent contact and contain runoff. Use alcohol-resistant foam, dry chemical, CO2 or water spray for fire and container cooling as conditions allow.

Firefighter training notes: Train crews on corrosive amine response, decon and alkaline runoff control. Include vapor monitoring and container cooling tactics.

Regulatory context: UN 2565 is transported as Dicyclohexylamine, Class 8 corrosive. Confirm quantity, packaging and emergency contact information.

Storage & handling: Store in closed containers in a cool, ventilated corrosive/combustible liquid area away from acids, oxidizers and heat.

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UN 2565 Quick Details

UN 2565
Product name: Dicyclohexylamine
DOT Class: 8
Placard type: Corrosive
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions

Common Hazards of UN 2565

  • Dicyclohexylamine is corrosive; skin or eye contact can cause severe burns.
  • Inhalation of vapor or mist can irritate or damage the respiratory tract.
  • It is combustible and may burn when heated or exposed to flame.
  • Fire may produce toxic nitrogen oxide fumes and irritating smoke.
  • Runoff can be alkaline, corrosive and harmful to waterways.
  • Vapors may form ignitable mixtures when heated in confined spaces.
  • Containers may rupture when heated.

Chemical Identity & Physical Properties

Dicyclohexylamine is a clear to pale yellow liquid with a fishy amine odor. It may solidify near 0°C.

Also known asDCHADodecahydrodiphenylamineN-CyclohexylcyclohexanamineBis(cyclohexyl)amine
CAS Number101-83-7
AppearanceClear to pale yellow liquid with a fishy amine odor. Solidifies at approximately 0°C (32°F).
Flash Point99°C (210°F)
Boiling Point256°C (493°F)
Vapor Density3.6 (heavier than air)
Water ReactivityNo significant reaction with water, but forms alkaline solutions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2565

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical, water spray for cooling

PPE Requirements

⚠️ Level B minimum; SCBA and chemical-resistant suit required; severe skin and eye corrosion hazard

Use SCBA for vapor, mist or fire conditions. Wear chemical-resistant suit, gloves, boots and full eye/face protection.

Isolation & Evacuation

ERG 153: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2565 Incident

  • Call 911 and the emergency response number on the shipping papers.
  • Keep unauthorized personnel away and establish an upwind control area.
  • Stay upwind, uphill and upstream of vapor, mist and runoff.
  • Avoid breathing vapor or mist; prevent all skin and eye contact.
  • Do not touch damaged containers or spilled liquid without chemical-resistant PPE.
  • Ventilate confined spaces only with trained personnel, SCBA and monitoring.
  • Use ERG 153, SDS and shipping papers for isolation, decon and cleanup decisions.
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📋 Copy & Share Field Card

UN 2565 — Dicyclohexylamine
HAZMAT RADIO NOTE — UN 2565 Product: Dicyclohexylamine Class 8 / Corrosive / ERG 153 PPE: Level B minimum; SCBA and chemical-resistant suit required; severe skin and eye corrosion hazard ISOLATION: ERG 153: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2565 — Dicyclohexylamine Class: 8 | Placard: Corrosive | ERG Guide: 153 Appearance: Clear to pale yellow liquid with a fishy amine odor. Solidifies at approximately 0°C (32°F). Water Reactivity: No significant reaction with water, but forms alkaline solutions Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling PPE: Level B minimum; SCBA and chemical-resistant suit required; severe skin and eye corrosion hazard Isolation: ERG 153: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions — Key Hazards — • Dicyclohexylamine is corrosive; skin or eye contact can cause severe burns. • Inhalation of vapor or mist can irritate or damage the respiratory tract. • It is combustible and may burn when heated or exposed to flame. — First Actions — • Call 911 and the emergency response number on the shipping papers. • Keep unauthorized personnel away and establish an upwind control area. • Stay upwind, uphill and upstream of vapor, mist and runoff. • Avoid breathing vapor or mist; prevent all skin and eye contact. SOURCE: allfirefighter.com/hazmat/un/dicyclohexylamine-un-2565 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2565 Dicyclohexylamine Cls8 ERG153 | allfirefighter.com/hazmat/un/dicyclohexylamine-un-2565SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/dicyclohexylamine-un-2565

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2565

Yes. It can cause severe skin and eye burns.

It is combustible rather than highly flammable, and can burn when heated or exposed to flame.

Fire may produce toxic nitrogen oxides and irritating smoke.

Runoff may be alkaline, corrosive and harmful to waterways.

SCBA plus chemical-resistant clothing, gloves, boots and eye/face protection are needed.

Use ERG 153 with the SDS and shipping papers.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.