☣️ UN 1325 • CLASS 4

UN 1325 — Flammable solid, organic, n.o.s.

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1325 is Flammable solid, organic, n.o.s., a Class 4 flammable solid assigned to ERG Guide 133. It may burn as powder, granules, lumps or molten material depending on the exact product and fire conditions.

Hazard overview: UN 1325 presents flammable solid, dust and smoke hazards. Powders can burn rapidly or form dust-air mixtures, while fire may produce irritating smoke and contaminated residue.

Response guidance: For a UN 1325 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 133. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors, dust or runoff out of drains where relevant, and use compatible fire-control agents from a protected position.

Firefighter training notes: Training for UN 1325 should emphasize dust fire behavior, rapid surface burning, smoke exposure, compatible extinguishment and avoiding dust cloud generation. Use ERG 133, SDS and local SOP.

Regulatory context: Flammable solid, organic, n.o.s. is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Flammable solid, organic, n.o.s. should be stored in compatible containers in a cool, dry, well-ventilated area away from heat, sparks, open flames, oxidizers and incompatible materials. Prevent dust release, friction, impact and unauthorized access.

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UN 1325 Quick Details

UN 1325
Product name: Flammable solid, organic, n.o.s.
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: Initial isolation 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions

Common Hazards of UN 1325

  • FLAMMABLE solid; may be ignited by heat, sparks, friction or flames.
  • Powders, dusts, shavings or small particles may burn rapidly or explosively in air.
  • Some materials may re-ignite after apparent extinguishment.
  • Fire may produce irritating or toxic smoke.
  • Molten or softened material may spread fire if heated.
  • Runoff from fire control may carry contaminated residue.
  • Specific hazards depend on the exact product and should be verified from SDS.

Chemical Identity & Physical Properties

Generic entry covering various organic solids. Appearance varies by specific material but typically solid at room temperature, may be crystalline, powder, or granular form. Color and odor depend on the specific substance.

Also known asFlammable solid organic NOSCombustible solid organicFlammable organic solid not otherwise specifiedUN1325
AppearanceGeneric entry covering various organic solids. Appearance varies by specific material but typically solid at room temperature, may be crystalline, powder, or granular form. Color and odor depend on the specific substance.
Flash PointNot applicable (flammable solid)
Boiling PointVaries by specific material
Vapor DensityNot applicable (solid)
Water ReactivityGenerally no significant reaction with water, though specific materials may vary
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1325

Extinguishing Media

Use water spray, fog, foam, dry chemical or CO2 only when compatible with the specific material and incident command; avoid spreading dust or burning material.

PPE Requirements

⚠️ Level C minimum recommended; SCBA if involved in fire or heavy dust generation; protective gloves and clothing to prevent skin contact

Use SCBA for fire, smoke, dust or confined-space exposure. Gloves, eye protection and protective clothing should be selected from SDS; avoid dust generation and contaminated residue contact.

Isolation & Evacuation

ERG 133: Initial isolation 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 1325 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Avoid creating dust clouds or spreading powder during movement or cleanup.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or fire area and expand the perimeter if large quantities, dust clouds or fire involvement are present.
  • Use ERG Guide 133, shipping papers, SDS and incident command for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1325 — Flammable solid, organic, n.o.s.
HAZMAT RADIO NOTE — UN 1325 Product: Flammable solid, organic, n.o.s. Class 4 / Flammable Solid / ERG 133 PPE: Level C minimum recommended; SCBA if involved in fire or heavy dust generation; protective gloves and clothing to prevent skin contact ISOLATION: ERG 133: Initial isolation 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1325 — Flammable solid, organic, n.o.s. Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: Generic entry covering various organic solids. Appearance varies by specific material but typically solid at room temperature, may be crystalline, powder, or granular form. Color and odor depend on the specific substance. Water Reactivity: Generally no significant reaction with water, though specific materials may vary Extinguishing: Use water spray, fog, foam, dry chemical or CO2 only when compatible with the specific material and incident command; avoid spreading dust or burning material. PPE: Level C minimum recommended; SCBA if involved in fire or heavy dust generation; protective gloves and clothing to prevent skin contact Isolation: ERG 133: Initial isolation 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions — Key Hazards — • FLAMMABLE solid; may be ignited by heat, sparks, friction or flames. • Powders, dusts, shavings or small particles may burn rapidly or explosively in air. • Some materials may re-ignite after apparent extinguishment. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/flammable-solid-organic-n-un-1325 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1325 Flammable solid, organic, n.o.s. Cls4 ERG133 | allfirefighter.com/hazmat/un/flammable-solid-organic-n-un-1325SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/flammable-solid-organic-n-un-1325

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1325

UN 1325 is Flammable solid, organic, n.o.s., a hazardous material assigned to ERG Guide 133.

Yes. It is a flammable solid and may ignite from heat, sparks, friction or flames.

ERG Guide 133 applies to UN 1325 for initial isolation, protective actions and first response guidance.

UN 1325 presents flammable solid, dust and smoke hazards. Powders can burn rapidly or form dust-air mixtures, while fire may produce irritating smoke and contaminated residue.

Yes. Powder or dust can burn rapidly and may form a dust-air explosion hazard depending on the exact material.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.