☣️ UN 1618 • CLASS 6

UN 1618 — Lead arsenites

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Lead arsenites are highly toxic substances that can be fatal if inhaled, ingested or absorbed through skin. They are often used in pesticides and fertilizers.

Hazard overview: Lead arsenites are highly toxic and may be fatal if inhaled, ingested or absorbed through skin. They can also contaminate water sources.

Response guidance: In case of emergency, isolate the spill area and evacuate the area. Use water spray, dry chemical or CO2 for adjacent fires.

Advertisement

UN 1618 Quick Details

UN 1618
Product name: Lead arsenites
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: Isolate spill area at least 25m in all directions; if large spill or fire involved, isolate 800m and consider evacuation

Common Hazards of UN 1618

  • Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
  • Avoid any skin contact.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
  • Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
  • Containers may explode when heated.
  • Runoff may pollute waterways.

Chemical Identity & Physical Properties

Lead arsenites are a white to grayish-white powder or crystalline solid, odorless and stable at room temperature as a solid.

Also known asLead arseniteArsenious acid lead saltLead(II) arsenitePlumbous arsenite
AppearanceWhite to grayish-white powder or crystalline solid. Odorless. Stable at room temperature as a solid.
Flash PointNot applicable (non-combustible inorganic solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid material)
Water ReactivitySlightly soluble in water; releases toxic arsenic compounds upon dissolution
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1618

Extinguishing Media

Water spray, dry chemical, CO2; foam not typically required for non-combustible material

PPE Requirements

⚠️ Level A or B required; full-face SCBA, chemical-resistant suit, double gloves; avoid any skin contact due to extreme toxicity

Use Level A or B PPE with full-face SCBA, chemical-resistant suit and double gloves.

Isolation & Evacuation

ERG 151: Isolate spill area at least 25m in all directions; if large spill or fire involved, isolate 800m and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1618 Incident

  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
  • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
  • For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
Advertisement

📋 Copy & Share Field Card

UN 1618 — Lead arsenites
HAZMAT RADIO NOTE — UN 1618 Product: Lead arsenites Class 6 / Toxic / ERG 151 PPE: Level A or B required; full-face SCBA, chemical-resistant suit, double gloves; avoid any skin contact due to extreme toxicity ISOLATION: ERG 151: Isolate spill area at least 25m in all directions; if large spill or fire involved, isolate 800m and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1618 — Lead arsenites Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: White to grayish-white powder or crystalline solid. Odorless. Stable at room temperature as a solid. Water Reactivity: Slightly soluble in water; releases toxic arsenic compounds upon dissolution Extinguishing: Water spray, dry chemical, CO2; foam not typically required for non-combustible material PPE: Level A or B required; full-face SCBA, chemical-resistant suit, double gloves; avoid any skin contact due to extreme toxicity Isolation: ERG 151: Isolate spill area at least 25m in all directions; if large spill or fire involved, isolate 800m and consider evacuation — Key Hazards — • Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. • Avoid any skin contact. • Fire may produce irritating, corrosive and/or toxic gases. — First Actions — • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances. SOURCE: allfirefighter.com/hazmat/un/lead-arsenites-un-1618 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1618 Lead arsenites Cls6 ERG151 | allfirefighter.com/hazmat/un/lead-arsenites-un-1618SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/lead-arsenites-un-1618

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 1618

No, material itself is non-combustible.

Yes, releases toxic arsenic compounds upon dissolution.

Level A or B with full-face SCBA, chemical-resistant suit and double gloves.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.