☣️ UN 2878 • CLASS 4

UN 2878 — Titanium sponge granules

Placard: Flammable Solid. ERG Guide 170. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2878 is Titanium sponge granules, a flammable metal granule/powder entry assigned to ERG Guide 170. Dust, re-ignition and Class D tactics are important.

Hazard overview: FLAMMABLE metal granules or powder; finely divided material may ignite from heat, sparks or friction. Burning titanium can produce intense heat and may re-ignite after apparent extinguishment. Dust or fines may form explosive mixtures in air.

Response guidance: For UN 2878, isolate the area, avoid dust/friction and use SCBA. Use compatible dry or specialist media, protect exposures and watch for re-ignition or violent decomposition under ERG 170.

Firefighter training notes: Training for UN 2878 should emphasize dust/friction control, compatible media, re-ignition, remote cooling, SCBA use and runoff/debris control. Use ERG 170, SDS and local SOP.

Regulatory context: Titanium sponge granules is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on package type, quantity, formulation and jurisdiction; verify shipping papers, SDS or authority guidance.

Storage & handling: Titanium sponge granules should be stored in tightly closed compatible containers away from heat, sparks, friction, moisture where incompatible, oxidizers/reducing agents as applicable and combustible contamination.

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UN 2878 Quick Details

UN 2878
Product name: Titanium sponge granules
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 170 (check current ERG)
Initial isolation: ERG 170: isolate 25m in all directions; for large spills isolate 50m and evacuate downwind areas

Common Hazards of UN 2878

  • FLAMMABLE metal granules or powder; finely divided material may ignite from heat, sparks or friction.
  • Burning titanium can produce intense heat and may re-ignite after apparent extinguishment.
  • Dust or fines may form explosive mixtures in air.
  • Water can intensify burning metal reactions or generate hydrogen when material is hot or finely divided.
  • Fire may produce titanium oxide fumes and metal smoke.
  • Containers may rupture or fail when heated.
  • Avoid creating dust, sparks or friction during handling.

Chemical Identity & Physical Properties

Gray to dark gray porous metallic granules or powder with a metallic appearance. Odorless solid at room temperature with a sponge-like structure.

Also known asTitanium spongeTitanium powderTitanium metal granulesSponge titanium
CAS Number7440-32-6
AppearanceGray to dark gray porous metallic granules or powder with a metallic appearance. Odorless solid at room temperature with a sponge-like structure.
Flash PointNot applicable (pyrophoric metal)
Boiling Point3287C (5949F)
Vapor DensityNot applicable (solid)
Water ReactivityMay react with water when finely divided or heated, releasing flammable hydrogen gas and heat
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2878

Extinguishing Media

Use dry Class D powder, dry sand, dry graphite or SDS-approved dry media. Do not use water or foam on burning titanium metal.

PPE Requirements

⚠️ Level B minimum with SCBA; face shield, heat-resistant gloves; avoid friction or spark sources

Use positive-pressure SCBA for fire, dust or smoke. Wear flame/heat-resistant and chemical-resistant protection; avoid dust clouds, friction and incompatible media.

Isolation & Evacuation

ERG 170: isolate 25m in all directions; for large spills isolate 50m and evacuate downwind areas
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 170).

First Actions for a UN 2878 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, gas, mist, smoke or aerosols and avoid skin or eye contact.
  • Avoid incompatible water, moisture or contamination controls that could intensify fire or reaction.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated liquid, dust, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 170, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2878 — Titanium sponge granules
HAZMAT RADIO NOTE — UN 2878 Product: Titanium sponge granules Class 4 / Flammable Solid / ERG 170 PPE: Level B minimum with SCBA; face shield, heat-resistant gloves; avoid friction or spark sources ISOLATION: ERG 170: isolate 25m in all directions; for large spills isolate 50m and evacuate downwind areas ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2878 — Titanium sponge granules Class: 4 | Placard: Flammable Solid | ERG Guide: 170 Appearance: Gray to dark gray porous metallic granules or powder with a metallic appearance. Odorless solid at room temperature with a sponge-like structure. Water Reactivity: May react with water when finely divided or heated, releasing flammable hydrogen gas and heat Extinguishing: Use dry Class D powder, dry sand, dry graphite or SDS-approved dry media. Do not use water or foam on burning titanium metal. PPE: Level B minimum with SCBA; face shield, heat-resistant gloves; avoid friction or spark sources Isolation: ERG 170: isolate 25m in all directions; for large spills isolate 50m and evacuate downwind areas — Key Hazards — • FLAMMABLE metal granules or powder; finely divided material may ignite from heat, sparks or friction. • Burning titanium can produce intense heat and may re-ignite after apparent extinguishment. • Dust or fines may form explosive mixtures in air. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, gas, mist, smoke or aerosols and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/titanium-sponge-granules-un-2878 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2878 Titanium sponge granules Cls4 ERG170 | allfirefighter.com/hazmat/un/titanium-sponge-granules-un-2878SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/titanium-sponge-granules-un-2878

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2878

UN 2878 is Titanium sponge granules, assigned to ERG Guide 170.

Yes. Titanium sponge granules is a flammable/spontaneously combustible solid and may re-ignite after apparent extinguishment.

FLAMMABLE metal granules or powder; finely divided material may ignite from heat, sparks or friction. Burning titanium can produce intense heat and may re-ignite after apparent extinguishment. Dust or fines may form explosive mixtures in air.

Use positive-pressure SCBA for fire, dust or smoke. Wear flame/heat-resistant and chemical-resistant protection; avoid dust clouds, friction and incompatible media.

Use dry Class D powder, dry sand, dry graphite or SDS-approved dry media. Do not use water or foam on burning titanium metal.

Avoid direct water unless specialist guidance confirms compatibility; burning metal or pyrophoric catalyst may react or spread.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.