☣️ UN 0220 • CLASS 1

UN 0220 — Urea nitrate, dry

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0220, Urea Nitrate (also known as Carbamide Nitrate or Urea Mononitrate), is a dry crystalline explosive classified as a Class 1.1D mass explosion hazard. Emergency responders must treat any incident involving this material with extreme caution due to its sensitivity to heat, shock, and friction.

Hazard overview: UN 0220 presents a mass explosion hazard, meaning the entire load may detonate simultaneously, producing severe blast overpressure and fragmentation capable of causing casualties at significant distances. The material is sensitive to heat, shock, and friction, making any physical disturbance or fire exposure a potentially catastrophic trigger.

Response guidance: For any incident involving UN 0220, establish an immediate isolation zone of at least 500 meters in all directions and expand downwind evacuation to 1,600 meters if fire is present or imminent. Do not apply water to bulk quantities of Urea Nitrate, as this creates a disposal hazard; use dry chemical or sand only for small, contained fires.

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UN 0220 Quick Details

UN 0220
Product name: Urea nitrate, dry
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire involves explosive

Common Hazards of UN 0220

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0220 Urea Nitrate is a white to pale yellow odorless crystalline solid that is hygroscopic and prone to caking or clumping when exposed to moisture.

Also known asCarbamide nitrateUrea mononitrateNitro ureaUranitraat
CAS Number124-47-0
AppearanceWhite to pale yellow crystalline solid. Odorless. Hygroscopic and may cake or clump in moist conditions.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes/detonates before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityDissolves in water; reduces sensitivity but creates disposal hazard
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0220

Extinguishing Media

Do not use water on bulk quantities; dry chemical or sand for small fires only

PPE Requirements

⚠️ Level B minimum with face shield; SCBA mandatory; minimize personnel in hazard zone

Responders must wear a minimum of Level B protection with a full face shield and mandatory SCBA, while keeping the number of personnel in the hazard zone to an absolute minimum.

Isolation & Evacuation

ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire involves explosive
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0220 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0220 — Urea nitrate, dry
HAZMAT RADIO NOTE — UN 0220 Product: Urea nitrate, dry Class 1 / Explosive 1.1D / ERG 112 PPE: Level B minimum with face shield; SCBA mandatory; minimize personnel in hazard zone ISOLATION: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire involves explosive ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0220 — Urea nitrate, dry Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White to pale yellow crystalline solid. Odorless. Hygroscopic and may cake or clump in moist conditions. Water Reactivity: Dissolves in water; reduces sensitivity but creates disposal hazard Extinguishing: Do not use water on bulk quantities; dry chemical or sand for small fires only PPE: Level B minimum with face shield; SCBA mandatory; minimize personnel in hazard zone Isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire involves explosive — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/urea-nitrate-dry-un-0220 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0220 Urea nitrate, dry Cls1 ERG112 | allfirefighter.com/hazmat/un/urea-nitrate-dry-un-0220SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/urea-nitrate-dry-un-0220

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0220

UN 0220 Urea Nitrate is classified as a Class 1.1D explosive, meaning it poses a mass explosion hazard rather than a simple flammability risk, and the entire load can detonate simultaneously when subjected to heat, shock, or friction.

Responders handling a UN 0220 incident must use at minimum Level B chemical protective equipment with a full face shield and self-contained breathing apparatus (SCBA), with personnel in the hazard zone kept to the bare minimum.

Per ERG Guide 112, the minimum isolation distance for UN 0220 is 500 meters in all directions, expanding to a 1,600-meter downwind evacuation if the material is involved in or threatened by fire.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.