☣️ UN 1383 • CLASS 4

UN 1383 — Aluminum powder, pyrophoric

Placard: Spontaneously Combustible. ERG Guide 135. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1383 is Aluminum powder, pyrophoric, a self-heating or spontaneously combustible material assigned to ERG Guide 135. The main hazard is hidden heat buildup that can lead to smoldering, open flame or re-ignition.

Hazard overview: UN 1383 presents self-heating, smoldering fire and re-ignition hazards. Disturbing hot material can introduce oxygen and intensify burning, while smoke may contain carbon monoxide and irritating combustion products.

Response guidance: For a UN 1383 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 135. Establish incident command, isolate the area, stay upwind, avoid unnecessary disturbance of powder, piles or damaged packaging, and use only extinguishing agents compatible with the specific material.

Firefighter training notes: Training for UN 1383 should emphasize self-heating, smoldering piles, oxygen exposure during overhaul, thermal monitoring and re-ignition. Common errors include opening hot piles too aggressively and ending operations before deep-seated heat is controlled.

Regulatory context: Aluminum powder, pyrophoric is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Aluminum powder, pyrophoric should be stored to prevent self-heating, oil/moisture contamination where relevant, compacted hot spots and ignition exposure. Keep piles, bales or packages ventilated where appropriate and inspect for heat, odor or smoke according to facility procedures.

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UN 1383 Quick Details

UN 1383
Product name: Aluminum powder, pyrophoric
DOT Class: 4
Placard type: Spontaneously Combustible
ERG Guide: 135 (check current ERG)
Initial isolation: ERG 135: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation

Common Hazards of UN 1383

  • May self-heat and ignite when damp, oily, contaminated, compacted or stored in bulk.
  • Piles, sacks, bales or rolls may retain heat and smolder internally before open flame is visible.
  • Disturbing hot material may introduce oxygen and intensify smoldering or flame spread.
  • Fire may produce irritating or toxic smoke including carbon monoxide.
  • Runoff from fire control may carry organic or oily contamination.
  • Large quantities may require prolonged overhaul and thermal monitoring.
  • Material may re-ignite after apparent extinguishment.

Chemical Identity & Physical Properties

Fine gray to silver-gray metallic powder with no odor. Pyrophoric grade ignites spontaneously in air, especially when moist.

Also known asPyrophoric aluminumAluminum metal powderAluminium powder (pyrophoric)Aluminum dust
CAS Number7429-90-5
AppearanceFine gray to silver-gray metallic powder with no odor. Pyrophoric grade ignites spontaneously in air, especially when moist.
Flash PointNot applicable (pyrophoric solid, self-ignites)
Boiling Point2519C (4566F)
Vapor DensityNot applicable (solid)
Water ReactivityReacts with water/moisture generating hydrogen gas and heat; may ignite spontaneously
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1383

Extinguishing Media

Use water spray, fog, foam, dry chemical, CO2 or sand only when compatible with the specific material and incident command; avoid spreading dust, oil or burning material.

PPE Requirements

⚠️ Level B minimum with SCBA; fire-resistant clothing for fire situations; avoid creating dust

Use SCBA for smoke, smoldering material, dust or confined-space operations. Wear protective clothing and gloves appropriate for hot organic material, contaminated runoff and extended overhaul conditions.

Isolation & Evacuation

ERG 135: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 135).

First Actions for a UN 1383 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Check for heat, smoke, odor or smoldering before disturbing piles, bales, sacks or containers.
  • Avoid breaking apart hot material unless incident command has a controlled plan for exposure, extinguishment and overhaul.
  • Isolate the area and remove ignition sources if it is safe to do so.
  • Use thermal imaging, monitoring and extended overhaul where available.
  • Use ERG Guide 135, shipping papers, SDS and local SOP for protective actions and fire-control decisions.
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📋 Copy & Share Field Card

UN 1383 — Aluminum powder, pyrophoric
HAZMAT RADIO NOTE — UN 1383 Product: Aluminum powder, pyrophoric Class 4 / Spontaneously Combustible / ERG 135 PPE: Level B minimum with SCBA; fire-resistant clothing for fire situations; avoid creating dust ISOLATION: ERG 135: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1383 — Aluminum powder, pyrophoric Class: 4 | Placard: Spontaneously Combustible | ERG Guide: 135 Appearance: Fine gray to silver-gray metallic powder with no odor. Pyrophoric grade ignites spontaneously in air, especially when moist. Water Reactivity: Reacts with water/moisture generating hydrogen gas and heat; may ignite spontaneously Extinguishing: Use water spray, fog, foam, dry chemical, CO2 or sand only when compatible with the specific material and incident command; avoid spreading dust, oil or burning material. PPE: Level B minimum with SCBA; fire-resistant clothing for fire situations; avoid creating dust Isolation: ERG 135: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation — Key Hazards — • May self-heat and ignite when damp, oily, contaminated, compacted or stored in bulk. • Piles, sacks, bales or rolls may retain heat and smolder internally before open flame is visible. • Disturbing hot material may introduce oxygen and intensify smoldering or flame spread. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Check for heat, smoke, odor or smoldering before disturbing piles, bales, sacks or containers. SOURCE: allfirefighter.com/hazmat/un/aluminum-powder-pyrophoric-un-1383 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1383 Aluminum powder, pyrophoric Cls4 ERG135 | allfirefighter.com/hazmat/un/aluminum-powder-pyrophoric-un-1383SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/aluminum-powder-pyrophoric-un-1383

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1383

UN 1383 is Aluminum powder, pyrophoric, a hazardous material assigned to ERG Guide 135.

Yes, it can become a fire hazard through self-heating, drying, oil contamination or smoldering conditions.

ERG Guide 135 applies to UN 1383 for initial isolation, protective actions and first response guidance.

UN 1383 presents self-heating, smoldering fire and re-ignition hazards. Disturbing hot material can introduce oxygen and intensify burning, while smoke may contain carbon monoxide and irritating combustion products.

Self-heating or deep smoldering can remain inside piles, sacks, bales or rolls after visible flame is gone, so overhaul and thermal monitoring matter.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.