☣️ UN 1621 • CLASS 6

UN 1621 — London purple

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 1621 Quick Details

UN 1621
Product name: London purple
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate downwind areas if airborne

Common Hazards of UN 1621

  • Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
  • Avoid any skin contact.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
  • Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
  • Containers may explode when heated.
  • Runoff may pollute waterways.

Chemical Identity & Physical Properties

Also known asArsenite of limeCalcium arseniteLondon purple insecticideArsenical dustPurple dye
CAS Number8028-73-7
AppearancePurple to violet-colored powder or crystalline solid. Odorless to slight metallic odor. Solid at room temperature.
Flash PointNot applicable (non-combustible solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivitySlowly soluble in water, may release toxic arsenic compounds
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1621

Extinguishing Media

Water spray, dry chemical, sand; avoid creating dust clouds

PPE Requirements

⚠️ Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid skin contact completely

Isolation & Evacuation

ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate downwind areas if airborne
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1621 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
  • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
  • For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card

UN 1621 — London purple
HAZMAT RADIO NOTE — UN 1621 Product: London purple Class 6 / Toxic / ERG 151 PPE: Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid skin contact completely ISOLATION: ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate downwind areas if airborne ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1621 — London purple Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Purple to violet-colored powder or crystalline solid. Odorless to slight metallic odor. Solid at room temperature. Water Reactivity: Slowly soluble in water, may release toxic arsenic compounds Extinguishing: Water spray, dry chemical, sand; avoid creating dust clouds PPE: Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid skin contact completely Isolation: ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate downwind areas if airborne — Key Hazards — • Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. • Avoid any skin contact. • Fire may produce irritating, corrosive and/or toxic gases. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters SOURCE: allfirefighter.com/hazmat/un/1621 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN1621 London purple Cls6 ERG151 | ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate | allfirefighter.com/hazmat/un/1621SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1621

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1621

Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Containers may explode when heated. Runoff may pollute waterways.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid skin contact completely

Water reactivity: Slowly soluble in water, may release toxic arsenic compounds. Recommended extinguishing: Water spray, dry chemical, sand; avoid creating dust clouds.

ERG Guide 151 recommendation: ERG 151: isolate spill 25m all directions; if large spill isolate 50m; evacuate downwind areas if airborne

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 151 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.