☣️ UN 1651 • CLASS 6

UN 1651 — Naphthylthiourea

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1651 is Naphthylthiourea, a toxic organic solid assigned to ERG Guide 153. Responders should avoid dust exposure, skin contact and contaminated runoff.

Hazard overview: UN 1651 presents toxic dust, ingestion and skin-contact hazards. Fire may produce irritating or toxic gases, and dry powder can contaminate clothing, tools and surfaces.

Response guidance: For a UN 1651 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1651 should emphasize toxic dust exposure, combustible organic solid behavior, PPE selection, decontamination and runoff control. Use ERG 153, SDS and local SOP.

Regulatory context: Naphthylthiourea is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Naphthylthiourea should be stored in tightly closed compatible containers in a secure toxic-material area according to SDS and local hazardous materials procedures.

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UN 1651 Quick Details

UN 1651
Product name: Naphthylthiourea
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25m all directions; for large spill isolate 50m; if fire/large spill consider evacuation 800m downwind

Common Hazards of UN 1651

  • TOXIC organic solid; inhalation, ingestion or skin contact may cause serious injury.
  • Dust can create inhalation and surface contamination hazards.
  • Combustible material: may burn but does not ignite readily.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may carry toxic contamination to drains or waterways.
  • Containers may rupture or fail when heated.
  • Specific toxicity depends on formulation and should be verified from SDS.

Chemical Identity & Physical Properties

White to gray odorless crystalline powder or solid at room temperature. May have a slight bitter taste.

Also known asANTUAlpha-naphthylthiourea1-NaphthylthioureaRattrackBantu
CAS Number86-88-4
AppearanceWhite to gray odorless crystalline powder or solid at room temperature. May have a slight bitter taste.
Flash PointNot applicable (non-flammable solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1651

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination.

PPE Requirements

⚠️ Level B minimum with SCBA; avoid all skin contact, use chemical-resistant protective clothing and gloves

Use positive-pressure SCBA for dust, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid dust and contaminated skin contact.

Isolation & Evacuation

ERG 153: isolate spill 25m all directions; for large spill isolate 50m; if fire/large spill consider evacuation 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 1651 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated liquid, powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1651 — Naphthylthiourea
HAZMAT RADIO NOTE — UN 1651 Product: Naphthylthiourea Class 6 / Toxic / ERG 153 PPE: Level B minimum with SCBA; avoid all skin contact, use chemical-resistant protective clothing and gloves ISOLATION: ERG 153: isolate spill 25m all directions; for large spill isolate 50m; if fire/large spill consider evacuation 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1651 — Naphthylthiourea Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: White to gray odorless crystalline powder or solid at room temperature. May have a slight bitter taste. Water Reactivity: No significant reaction with water Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination. PPE: Level B minimum with SCBA; avoid all skin contact, use chemical-resistant protective clothing and gloves Isolation: ERG 153: isolate spill 25m all directions; for large spill isolate 50m; if fire/large spill consider evacuation 800m downwind — Key Hazards — • TOXIC organic solid; inhalation, ingestion or skin contact may cause serious injury. • Dust can create inhalation and surface contamination hazards. • Combustible material: may burn but does not ignite readily. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/naphthylthiourea-un-1651 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1651 Naphthylthiourea Cls6 ERG153 | allfirefighter.com/hazmat/un/naphthylthiourea-un-1651SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/naphthylthiourea-un-1651

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1651

UN 1651 is Naphthylthiourea, a hazardous material assigned to ERG Guide 153.

It is generally not readily flammable, but organic solid material may burn under fire conditions.

ERG Guide 153 applies to UN 1651 for initial isolation, protective actions and first response guidance.

UN 1651 presents toxic dust, ingestion and skin-contact hazards. Fire may produce irritating or toxic gases, and dry powder can contaminate clothing, tools and surfaces.

Use positive-pressure SCBA for dust, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid dust and contaminated skin contact.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.