☣️ UN 2668 • CLASS 6
Chloroacetonitrile
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 2668
Class: 6
Placard type: Toxic
ERG: Guide 131 (check current ERG)
Isolation: ERG 131: isolate spill/leak area immediate 50m all directions; large spill isolate 150m in all directions; evacuate downwind 500m+ if fire or large spill
Chemical & Response Details
| Also known as | Chloromethyl cyanideMonochloroacetonitrile2-ChloroacetonitrileChloroacetic nitrile |
| CAS Number | 107-14-2 |
| Appearance | Colorless to pale yellow liquid with a pungent, irritating odor. Volatile and lachrymatory (causes tearing). |
| Flash Point | 56°C (133°F) |
| Boiling Point | 124-126°C (255-259°F) |
| Vapor Density | 2.6 (heavier than air) |
| Water Reactivity | Decomposes slowly in water, releasing toxic hydrogen cyanide and corrosive hydrochloric acid vapors |
| Extinguishing | Alcohol-resistant foam, CO2, dry chemical; water spray for cooling only |
| PPE | ⚠️ Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid all skin/eye contact due to severe toxicity and lachrymatory effects |
| Isolation | ERG 131: isolate spill/leak area immediate 50m all directions; large spill isolate 150m in all directions; evacuate downwind 500m+ if fire or large spill |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
- Inhalation or contact with some of these materials will irritate or burn skin and eyes.
- Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
- Fire will produce irritating, corrosive and/or toxic gases.
- Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas.
- Runoff from fire control or dilution water may cause environmental contamination.
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 2668 — Chloroacetonitrile HAZMAT RADIO NOTE — UN 2668
Product: Chloroacetonitrile
Class 6 / Toxic / ERG 131
PPE: Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid all skin/eye contact due to severe toxicity and lachrymatory effects
ISOLATION: ERG 131: isolate spill/leak area immediate 50m all directions; large spill isolate 150m in all directions; evacuate downwind 500m+ if fire or large spill
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2668 — Chloroacetonitrile
Class: 6 | Placard: Toxic | ERG Guide: 131
Appearance: Colorless to pale yellow liquid with a pungent, irritating odor. Volatile and lachrymatory (causes tearing).
Water Reactivity: Decomposes slowly in water, releasing toxic hydrogen cyanide and corrosive hydrochloric acid vapors
Extinguishing: Alcohol-resistant foam, CO2, dry chemical; water spray for cooling only
PPE: Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid all skin/eye contact due to severe toxicity and lachrymatory effects
Isolation: ERG 131: isolate spill/leak area immediate 50m all directions; large spill isolate 150m in all directions; evacuate downwind 500m+ if fire or large spill
— Key Hazards —
• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
• Inhalation or contact with some of these materials will irritate or burn skin and eyes.
• Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2668 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2668 Chloroacetonitrile Cls6 ERG131 | ERG 131: isolate spill/leak area immediate 50m all directions; large spill isola | allfirefighter.com/hazmat/un/2668SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/2668
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FAQ
TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas. Runoff from fire control or dilution water may cause environmental contamination. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A or B minimum; full-face SCBA required; chemical-resistant suit; avoid all skin/eye contact due to severe toxicity and lachrymatory effects
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 131 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.