☣️ UN 3415 • CLASS 6
Sodium fluoride, solution
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
Advertisement
Quick details
UN 3415
Class: 6
Placard type: Toxic
ERG: Guide 154 (check current ERG)
Isolation: ERG 154: Initial isolation 25m in all directions; protective action distance 0.1km daytime, 0.2km nighttime for small spills; increase distances for large spills or fire involvement
Chemical & Response Details
| Also known as | Sodium fluoride solutionDisodium difluoride solutionNatrium fluoride solutionNaF solution |
| CAS Number | 7681-49-4 |
| Appearance | Clear to slightly cloudy aqueous solution, odorless or faint chemical odor. Typically colorless liquid at room temperature. |
| Flash Point | Not applicable (aqueous solution, non-flammable) |
| Boiling Point | Approximately 100C (212F), similar to water depending on concentration |
| Vapor Density | Not applicable (aqueous solution) |
| Water Reactivity | Already in aqueous solution; no significant reaction with additional water |
| Extinguishing | Water spray, fog, or regular foam acceptable for fire control; solution itself does not support combustion |
| PPE | ⚠️ Level B minimum recommended; chemical-resistant gloves, splash goggles, face shield; SCBA for enclosed spaces or spills; acid-resistant protective clothing |
| Isolation | ERG 154: Initial isolation 25m in all directions; protective action distance 0.1km daytime, 0.2km nighttime for small spills; increase distances for large spills or fire involvement |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
- Contact with molten substance may cause severe burns to skin and eyes.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
- Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.).
- Corrosives in contact with metals may evolve flammable hydrogen gas.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
Advertisement
📋 Copy & Share
UN 3415 — Sodium fluoride, solution HAZMAT RADIO NOTE — UN 3415
Product: Sodium fluoride, solution
Class 6 / Toxic / ERG 154
PPE: Level B minimum recommended; chemical-resistant gloves, splash goggles, face shield; SCBA for enclosed spaces or spills; acid-resistant protective clothing
ISOLATION: ERG 154: Initial isolation 25m in all directions; protective action distance 0.1km daytime, 0.2km nighttime for small spills; increase distances for large spills or fire involvement
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3415 — Sodium fluoride, solution
Class: 6 | Placard: Toxic | ERG Guide: 154
Appearance: Clear to slightly cloudy aqueous solution, odorless or faint chemical odor. Typically colorless liquid at room temperature.
Water Reactivity: Already in aqueous solution; no significant reaction with additional water
Extinguishing: Water spray, fog, or regular foam acceptable for fire control; solution itself does not support combustion
PPE: Level B minimum recommended; chemical-resistant gloves, splash goggles, face shield; SCBA for enclosed spaces or spills; acid-resistant protective clothing
Isolation: ERG 154: Initial isolation 25m in all directions; protective action distance 0.1km daytime, 0.2km nighttime for small spills; increase distances for large spills or fire involvement
— Key Hazards —
• TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
• Contact with molten substance may cause severe burns to skin and eyes.
• Avoid any skin contact.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/3415 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3415 Sodium fluoride, solution Cls6 ERG154 | allfirefighter.com/hazmat/un/3415SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3415
Advertisement
FAQ
TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Corrosives in contact with metals may evolve flammable hydrogen gas.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum recommended; chemical-resistant gloves, splash goggles, face shield; SCBA for enclosed spaces or spills; acid-resistant protective clothing
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 154 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.