☣️ UN 1398 • CLASS 4

UN 1398 — Aluminum silicon powder, uncoated

Placard: Dangerous When Wet. ERG Guide 138. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1398 is Aluminum silicon powder, uncoated, a dangerous-when-wet Class 4 material assigned to ERG Guide 138. Contact with water or moisture can release flammable hydrogen gas, creating fire, toxic exposure or pressure hazards.

Hazard overview: UN 1398 presents water-reactive, ignition and reaction-gas hazards. Moisture can generate flammable hydrogen gas and heat, so responders should keep the material dry, control runoff and use only compatible dry agents under incident command.

Response guidance: For a UN 1398 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 138. Establish incident command, isolate the area, stay upwind, avoid unnecessary disturbance of powder, piles or damaged packaging, and use only extinguishing agents compatible with the specific material.

Firefighter training notes: Training for UN 1398 should emphasize dangerous-when-wet behavior, reaction gas identification, dry-agent selection and downwind gas control. Common errors include using water or foam directly, entering low areas without monitoring and underestimating re-ignition. Use ERG 138, SDS and hazmat SOP.

Regulatory context: Aluminum silicon powder, uncoated is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Aluminum silicon powder, uncoated should be stored in tightly closed compatible containers in a cool, dry, well-ventilated area away from water, moisture, acids, oxidizers, heat and ignition sources. Protect containers from damage and keep compatible dry spill-control media available where required.

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UN 1398 Quick Details

UN 1398
Product name: Aluminum silicon powder, uncoated
DOT Class: 4
Placard type: Dangerous When Wet
ERG Guide: 138 (check current ERG)
Initial isolation: ERG 138: Isolate spill area immediate 25m in all directions. For large spills isolate 50m. If fire, evacuate 800m radius. Keep material dry at all times.

Common Hazards of UN 1398

  • DANGEROUS WHEN WET; contact with water or moisture can release flammable hydrogen gas.
  • May ignite on contact with water or moist air.
  • Reaction with water may generate heat and pressure.
  • May be ignited by heat, sparks or flames and may re-ignite after apparent extinguishment.
  • Containers may rupture or explode when heated.
  • Runoff or water application may spread contamination and increase gas generation.
  • Avoid low, enclosed or poorly ventilated areas where reaction gases may accumulate.
  • Metal powder dust can ignite or form dust-air explosion hazards if dispersed.

Chemical Identity & Physical Properties

Gray to dark gray metallic powder. Odorless. Solid at room temperature with a fine to coarse granular texture.

Also known asAluminum-silicon alloy powderAl-Si powderFerrosilicon aluminum powderUncoated aluminum silicon powder
AppearanceGray to dark gray metallic powder. Odorless. Solid at room temperature with a fine to coarse granular texture.
Flash PointNot applicable (pyrophoric/water-reactive solid)
Boiling PointNot applicable (metal alloy powder)
Vapor DensityNot applicable (solid powder)
Water ReactivityReacts with water to produce flammable hydrogen gas. May ignite spontaneously on contact with water or moist air. Reaction can be vigorous to violent depending on moisture content.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1398

Extinguishing Media

Use dry sand, dry chemical, soda ash, dry lime, graphite or approved Class D/dry media only if compatible and directed by incident command. Do not apply water or foam directly because water contact can generate flammable hydrogen gas.

PPE Requirements

⚠️ Level B minimum for spills. SCBA and full protective clothing required for fires. Avoid all moisture contact. Use non-sparking tools.

Use positive-pressure SCBA for any suspected flammable hydrogen gas, fire, vapor or confined-space exposure. Chemical-resistant clothing, gloves and eye/face protection should be selected from SDS and incident command; air monitoring is important.

Isolation & Evacuation

ERG 138: Isolate spill area immediate 25m in all directions. For large spills isolate 50m. If fire, evacuate 800m radius. Keep material dry at all times.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 138).

First Actions for a UN 1398 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid low areas where flammable hydrogen gas may collect.
  • Do not touch spilled material or damaged containers unless properly trained and equipped.
  • Keep water, foam and moisture away from the released material unless incident command confirms a compatible cooling or control use.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if water contact, fire or gas generation is suspected.
  • Use ERG Guide 138, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1398 — Aluminum silicon powder, uncoated
HAZMAT RADIO NOTE — UN 1398 Product: Aluminum silicon powder, uncoated Class 4 / Dangerous When Wet / ERG 138 PPE: Level B minimum for spills. SCBA and full protective clothing required for fires. Avoid all moisture contact. Use non-sparking tools. ISOLATION: ERG 138: Isolate spill area immediate 25m in all directions. For large spills isolate 50m. If fire, evacuate 800m radius. Keep material dry at all times. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1398 — Aluminum silicon powder, uncoated Class: 4 | Placard: Dangerous When Wet | ERG Guide: 138 Appearance: Gray to dark gray metallic powder. Odorless. Solid at room temperature with a fine to coarse granular texture. Water Reactivity: Reacts with water to produce flammable hydrogen gas. May ignite spontaneously on contact with water or moist air. Reaction can be vigorous to violent depending on moisture content. Extinguishing: Use dry sand, dry chemical, soda ash, dry lime, graphite or approved Class D/dry media only if compatible and directed by incident command. Do not apply water or foam directly because water contact can generate flammable hydrogen gas. PPE: Level B minimum for spills. SCBA and full protective clothing required for fires. Avoid all moisture contact. Use non-sparking tools. Isolation: ERG 138: Isolate spill area immediate 25m in all directions. For large spills isolate 50m. If fire, evacuate 800m radius. Keep material dry at all times. — Key Hazards — • DANGEROUS WHEN WET; contact with water or moisture can release flammable hydrogen gas. • May ignite on contact with water or moist air. • Reaction with water may generate heat and pressure. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid low areas where flammable hydrogen gas may collect. SOURCE: allfirefighter.com/hazmat/un/aluminum-silicon-powder-uncoated-un-1398 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1398 Aluminum silicon powder, uncoated Cls4 ERG138 | allfirefighter.com/hazmat/un/aluminum-silicon-powder-uncoated-un-1398SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/aluminum-silicon-powder-uncoated-un-1398

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1398

UN 1398 is Aluminum silicon powder, uncoated, a hazardous material assigned to ERG Guide 138.

Yes. It can produce flammable hydrogen gas and may ignite when exposed to water or moist air.

ERG Guide 138 applies to UN 1398 for initial isolation, protective actions and first response guidance.

UN 1398 presents water-reactive, ignition and reaction-gas hazards. Moisture can generate flammable hydrogen gas and heat, so responders should keep the material dry, control runoff and use only compatible dry agents under incident command.

Use positive-pressure SCBA for any suspected flammable hydrogen gas, fire, vapor or confined-space exposure. Chemical-resistant clothing, gloves and eye/face protection should be selected from SDS and incident command; air monitoring is important.

Do not apply water or foam directly unless incident command and product guidance confirm a safe use, because water contact can generate flammable hydrogen gas and heat.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.