☣️ UN 1547 • CLASS 6

UN 1547 — Aniline

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1547 is Aniline, a toxic hazardous material assigned to ERG Guide 153. Responders should verify the exact product with shipping papers, container markings and SDS before close action.

Hazard overview: UN 1547 presents toxic exposure hazards by inhalation, ingestion or skin contact. Fire, decomposition or runoff may produce toxic contamination and require air monitoring, isolation and decontamination.

Response guidance: For a UN 1547 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent incompatible contact and choose extinguishing or spill-control actions based on ERG, SDS and local SOP.

Firefighter training notes: Training for UN 1547 should emphasize toxic exposure routes, dust/vapor control, SCBA use, decontamination and avoiding skin contact. Use ERG 153, SDS and local SOP.

Regulatory context: Aniline is regulated as a toxic hazardous material. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Aniline should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated toxic-material area away from food, combustibles where incompatible, heat and unauthorized access. Prevent dust release, leaks and contaminated runoff.

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UN 1547 Quick Details

UN 1547
Product name: Aniline
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill area 50m all directions. If tank/rail car involved in fire, isolate 800m all directions.

Common Hazards of UN 1547

  • TOXIC material; may be harmful or fatal if inhaled, ingested or absorbed through skin.
  • Avoid breathing vapors, dust or mist and avoid skin or eye contact.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may carry toxic contamination and may pollute waterways.
  • Containers may rupture or explode when heated.
  • Specific toxicity and absorption risk should be confirmed from shipping papers and SDS.

Chemical Identity & Physical Properties

Oily liquid, colorless to pale yellow or brown. Characteristic amine odor. Darkens on exposure to air and light.

Also known asPhenylamineAminobenzeneBenzenamineAniline oil
CAS Number62-53-3
AppearanceOily liquid, colorless to pale yellow or brown. Characteristic amine odor. Darkens on exposure to air and light.
Flash Point70C (158F)
Boiling Point184C (363F)
Vapor Density3.2 (heavier than air)
Water ReactivitySlightly soluble in water, no violent reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1547

Extinguishing Media

Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe.

PPE Requirements

⚠️ Level B minimum; SCBA required. Chemical-resistant suit and gloves due to skin absorption hazard.

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid all skin contact and contaminated dust.

Isolation & Evacuation

ERG 153: isolate spill area 50m all directions. If tank/rail car involved in fire, isolate 800m all directions.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 1547 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement or unknown concentration is present.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1547 — Aniline
HAZMAT RADIO NOTE — UN 1547 Product: Aniline Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA required. Chemical-resistant suit and gloves due to skin absorption hazard. ISOLATION: ERG 153: isolate spill area 50m all directions. If tank/rail car involved in fire, isolate 800m all directions. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1547 — Aniline Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Oily liquid, colorless to pale yellow or brown. Characteristic amine odor. Darkens on exposure to air and light. Water Reactivity: Slightly soluble in water, no violent reaction Extinguishing: Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe. PPE: Level B minimum; SCBA required. Chemical-resistant suit and gloves due to skin absorption hazard. Isolation: ERG 153: isolate spill area 50m all directions. If tank/rail car involved in fire, isolate 800m all directions. — Key Hazards — • TOXIC material; may be harmful or fatal if inhaled, ingested or absorbed through skin. • Avoid breathing vapors, dust or mist and avoid skin or eye contact. • Fire may produce irritating, corrosive and/or toxic gases. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/aniline-un-1547 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1547 Aniline Cls6 ERG153 | ERG 153: isolate spill area 50m all directions. If tank/rail car involved in fir | allfirefighter.com/hazmat/un/aniline-un-1547SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/aniline-un-1547

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1547

UN 1547 is Aniline, a hazardous material assigned to ERG Guide 153.

Flammability depends on the exact material, but toxic exposure is the main response concern.

ERG Guide 153 applies to UN 1547 for initial isolation, protective actions and first response guidance.

UN 1547 presents toxic exposure hazards by inhalation, ingestion or skin contact. Fire, decomposition or runoff may produce toxic contamination and require air monitoring, isolation and decontamination.

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid all skin contact and contaminated dust.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.