☣️ UN 1579 • CLASS 6

UN 1579 — Chloro toluidine hydrochloride, solid

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1579 is Chloro toluidine hydrochloride, solid, a toxic aromatic compound assigned to ERG Guide 153. It may be a solid or liquid, but responder priorities are skin absorption control, toxic smoke and runoff containment.

Hazard overview: UN 1579 presents toxic skin, inhalation and ingestion hazards. It may burn or decompose under fire conditions, producing irritating or toxic nitrogen/chlorine-containing gases.

Response guidance: For a UN 1579 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1579 should emphasize toxic aromatic compound exposure, skin absorption, dust/vapor control, runoff containment and toxic smoke. Use ERG 153, SDS and local SOP.

Regulatory context: Chloro toluidine hydrochloride, solid is regulated as a toxic hazardous material. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Chloro toluidine hydrochloride, solid should be stored in tightly closed compatible containers in a secure toxic-material area according to SDS and local hazardous materials procedures.

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UN 1579 Quick Details

UN 1579
Product name: Chloro toluidine hydrochloride, solid
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill area at least 25m in all directions; if fire involved, isolate 800m and consider evacuation for 800m downwind

Common Hazards of UN 1579

  • TOXIC aromatic nitro or amine compound; inhalation, ingestion or skin absorption may cause severe injury.
  • Combustible material: may burn but does not ignite readily.
  • Dust, vapor or molten/liquid contact may injure eyes, skin and respiratory tissue.
  • Vapors or decomposition products may be heavier than air and collect in low areas.
  • Fire may produce irritating, corrosive and/or toxic gases including nitrogen oxides and hydrogen chloride.
  • Runoff may be toxic and may pollute waterways.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

White to off-white or tan crystalline powder or solid. Odorless to slight amine-like odor. Solid at room temperature.

Also known as4-chloro-2-methylaniline hydrochloridep-chloro-o-toluidine hydrochloride2-methyl-4-chloroaniline hydrochloridePCOT hydrochloride
CAS Number3165-93-3
AppearanceWhite to off-white or tan crystalline powder or solid. Odorless to slight amine-like odor. Solid at room temperature.
Flash PointNot applicable (non-flammable solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction; soluble in water forming acidic solutions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1579

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination.

PPE Requirements

⚠️ Level B minimum; SCBA with full protective clothing; avoid all skin contact; chemical-resistant gloves and clothing mandatory

Use positive-pressure SCBA for vapor, dust, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because skin absorption may be significant.

Isolation & Evacuation

ERG 153: isolate spill area at least 25m in all directions; if fire involved, isolate 800m and consider evacuation for 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 1579 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated powder, molten material or runoff.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement or unknown concentration is present.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1579 — Chloro toluidine hydrochloride, solid
HAZMAT RADIO NOTE — UN 1579 Product: Chloro toluidine hydrochloride, solid Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA with full protective clothing; avoid all skin contact; chemical-resistant gloves and clothing mandatory ISOLATION: ERG 153: isolate spill area at least 25m in all directions; if fire involved, isolate 800m and consider evacuation for 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1579 — Chloro toluidine hydrochloride, solid Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: White to off-white or tan crystalline powder or solid. Odorless to slight amine-like odor. Solid at room temperature. Water Reactivity: No significant reaction; soluble in water forming acidic solutions Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination. PPE: Level B minimum; SCBA with full protective clothing; avoid all skin contact; chemical-resistant gloves and clothing mandatory Isolation: ERG 153: isolate spill area at least 25m in all directions; if fire involved, isolate 800m and consider evacuation for 800m downwind — Key Hazards — • TOXIC aromatic nitro or amine compound; inhalation, ingestion or skin absorption may cause severe injury. • Combustible material: may burn but does not ignite readily. • Dust, vapor or molten/liquid contact may injure eyes, skin and respiratory tissue. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/chloro-toluidine-un-1579 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1579 Chloro toluidine hydrochloride, solid Cls6 ERG153 | allfirefighter.com/hazmat/un/chloro-toluidine-un-1579SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/chloro-toluidine-un-1579

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1579

UN 1579 is Chloro toluidine hydrochloride, solid, a toxic hazardous material assigned to ERG Guide 153.

It may be combustible but does not ignite readily; toxic exposure and decomposition smoke are the main hazards.

ERG Guide 153 applies to UN 1579 for initial isolation, protective actions and first response guidance.

UN 1579 presents toxic skin, inhalation and ingestion hazards. It may burn or decompose under fire conditions, producing irritating or toxic nitrogen/chlorine-containing gases.

Use positive-pressure SCBA for vapor, dust, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because skin absorption may be significant.

Some toxic aromatic compounds can be absorbed through skin or contaminate clothing and gloves, so chemical-resistant PPE and decontamination matter.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.