☣️ UN 1750 • CLASS 6

UN 1750 — Chloroacetic acid, solution

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1750 is Chloroacetic acid, solution, a toxic corrosive acid assigned to ERG Guide 153. It can cause severe burns and systemic poisoning through skin contact.

Hazard overview: UN 1750 presents toxic skin absorption, corrosive burn, combustible solid/liquid and acidic runoff hazards. Contaminated clothing and molten material can extend exposure.

Response guidance: For a UN 1750 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff and choose entry or fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1750 should emphasize toxic/corrosive exposure routes, water or oxidizer incompatibility where applicable, air monitoring, PPE selection, decontamination and runoff containment. Use ERG 153, SDS and local SOP.

Regulatory context: Chloroacetic acid, solution is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Chloroacetic acid, solution should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated hazardous-material area according to SDS and local procedures.

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UN 1750 Quick Details

UN 1750
Product name: Chloroacetic acid, solution
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions; evacuate downwind areas if material is spilled

Common Hazards of UN 1750

  • TOXIC and CORROSIVE chloroacetic acid; inhalation, ingestion or skin contact may cause severe injury.
  • Skin absorption can be significant and contaminated clothing may continue exposure.
  • Solid or molten material can burn eyes, skin and respiratory tissue.
  • Combustible material: may burn under fire conditions.
  • Fire may produce hydrogen chloride and other toxic/corrosive gases.
  • Runoff may carry acidic toxic contamination.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Colorless to pale yellow crystalline solid or clear to slightly yellow solution. Pungent, acrid odor. Hygroscopic. Typically supplied as aqueous solution (50-80%).

Also known asMonochloroacetic acidMCAChloroethanoic acid2-Chloroacetic acid
CAS Number79-11-8
AppearanceColorless to pale yellow crystalline solid or clear to slightly yellow solution. Pungent, acrid odor. Hygroscopic. Typically supplied as aqueous solution (50-80%).
Flash Point126C (259F) for pure material; lower for aqueous solutions depending on concentration
Boiling Point189C (372F) for pure material; varies with solution concentration
Vapor Density3.3 (heavier than air)
Water ReactivitySoluble in water; no violent reaction but solutions are highly corrosive
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1750

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when runoff can be controlled as toxic/corrosive contamination.

PPE Requirements

⚠️ Level B minimum; SCBA required; chemical-resistant gloves and full protective suit; avoid all contact with skin and eyes

Use positive-pressure SCBA for vapor, fume, dust, fire or confined-space exposure. Chemical-resistant gloves, boots, eye/face protection and protective clothing should be selected from SDS; Level A may be needed for close entry or unknown concentrations.

Isolation & Evacuation

ERG 153: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions; evacuate downwind areas if material is spilled
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 1750 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist or gas and avoid skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, gas, dust, fire involvement, water reaction or unknown concentration is present.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1750 — Chloroacetic acid, solution
HAZMAT RADIO NOTE — UN 1750 Product: Chloroacetic acid, solution Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA required; chemical-resistant gloves and full protective suit; avoid all contact with skin and eyes ISOLATION: ERG 153: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions; evacuate downwind areas if material is spilled ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1750 — Chloroacetic acid, solution Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Colorless to pale yellow crystalline solid or clear to slightly yellow solution. Pungent, acrid odor. Hygroscopic. Typically supplied as aqueous solution (50-80%). Water Reactivity: Soluble in water; no violent reaction but solutions are highly corrosive Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when runoff can be controlled as toxic/corrosive contamination. PPE: Level B minimum; SCBA required; chemical-resistant gloves and full protective suit; avoid all contact with skin and eyes Isolation: ERG 153: isolate spill/leak area immediately 25-50m all directions; if tank/rail car involved in fire isolate 800m all directions; evacuate downwind areas if material is spilled — Key Hazards — • TOXIC and CORROSIVE chloroacetic acid; inhalation, ingestion or skin contact may cause severe injury. • Skin absorption can be significant and contaminated clothing may continue exposure. • Solid or molten material can burn eyes, skin and respiratory tissue. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist or gas and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/chloroacetic-acid-solution-un-1750 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1750 Chloroacetic acid, solution Cls6 ERG153 | allfirefighter.com/hazmat/un/chloroacetic-acid-solution-un-1750SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/chloroacetic-acid-solution-un-1750

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1750

UN 1750 is Chloroacetic acid, solution, a hazardous material assigned to ERG Guide 153.

It is combustible but does not ignite readily; toxic and corrosive exposure are the main response concerns.

ERG Guide 153 applies to UN 1750 for initial isolation, protective actions and first response guidance.

UN 1750 presents toxic skin absorption, corrosive burn, combustible solid/liquid and acidic runoff hazards. Contaminated clothing and molten material can extend exposure.

Use positive-pressure SCBA for vapor, fume, dust, fire or confined-space exposure. Chemical-resistant gloves, boots, eye/face protection and protective clothing should be selected from SDS; Level A may be needed for close entry or unknown concentrations.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.