☣️ UN 3026 • CLASS 6

UN 3026 — Coumarin derivative pesticide, liquid, poisonous

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Coumarin derivative pesticide, liquid, poisonous is a liquid pesticide formulation assigned to UN 3026. It should be treated as a toxic pesticide product until the active ingredient, carrier solvent and concentration are confirmed from shipping papers and the SDS.

Hazard overview: The main concern with UN 3026 is toxic exposure from the pesticide formulation. Dermal absorption, inhalation of vapors or dust, ingestion, contaminated runoff and toxic fire gases are the response priorities.

Response guidance: For UN 3026, isolate the spill area, keep personnel upwind and avoid all skin contact. Use absorbent or containment methods compatible with the formulation and keep contaminated runoff out of drains. Fire control should focus on exposed packaging and the carrier solvent if present; verify the SDS before choosing water or foam.

Firefighter training notes: Train responders to treat UN 3026 as a toxic pesticide release, verify the exact product, control runoff and avoid skin contact during rescue, containment and decon.

Regulatory context: UN 3026 is regulated for transport as a hazardous pesticide entry. Product labels, shipping papers, SDS and local environmental reporting rules should guide final actions.

Storage & handling: Store UN 3026 away from food, feed, drains, ignition sources where applicable and incompatible chemicals. Keep containers closed, labeled and protected from heat or physical damage.

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UN 3026 Quick Details

UN 3026
Product name: Coumarin derivative pesticide, liquid, poisonous
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: Isolate spill/leak area immediately for at least 50m in all directions; evacuate 800m downwind during fire; consider initial evacuation 100m in all directions

Common Hazards of UN 3026

  • Coumarin derivative pesticide formulations may be highly toxic by inhalation, ingestion or skin absorption.
  • Liquid contact can contaminate PPE and expose responders during doffing.
  • Fire or heating may release irritating, corrosive or toxic decomposition gases.
  • Containers may rupture when heated even when the product itself is not readily flammable.
  • Runoff from spill control or firefighting can carry pesticide contamination into waterways.
  • Some formulations contain solvents or surfactants that change vapor, foam and cleanup behavior.
  • Exact product identity and concentration must be verified from SDS and shipping papers.

Chemical Identity & Physical Properties

Clear to pale yellow or amber liquid with mild to no odor. Viscosity varies by formulation. Liquid state at room temperature. Product-specific appearance and odor should not be used as the only identification method.

Also known asCoumarin pesticideWarfarin-type pesticideAnticoagulant rodenticide liquidHydroxycoumarins pesticide
AppearanceClear to pale yellow or amber liquid with mild to no odor. Viscosity varies by formulation. Liquid state at room temperature.
Flash PointVaries by formulation and carrier solvent, typically 23-61C (73-142F) depending on petroleum distillate content
Boiling PointVaries by formulation, typically 150-300C (302-572F) depending on solvent and active ingredient concentration
Vapor DensityGreater than 1 (heavier than air) for most liquid formulations
Water ReactivityNo significant reaction with water, though may form emulsions or separate depending on formulation
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3026

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical, water spray for cooling. Avoid high-pressure water streams.

PPE Requirements

⚠️ Level A or B required; SCBA mandatory; fully encapsulating chemical-resistant suit; double nitrile gloves; highly toxic via all routes of exposure

Use positive-pressure SCBA and chemical-resistant protective clothing suitable for pesticide liquids. Gloves, boots and suit material should be selected from the SDS because permeation varies by active ingredient and solvent.

Isolation & Evacuation

ERG 151: Isolate spill/leak area immediately for at least 50m in all directions; evacuate 800m downwind during fire; consider initial evacuation 100m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 3026 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; avoid low areas where vapors may collect.
  • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact.
  • Do not touch damaged containers or spilled material without appropriate PPE.
  • Ventilate confined spaces only when trained, equipped and authorized.
  • Use ERG 151, SDS, shipping papers and monitoring to confirm product hazards before close approach.
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📋 Copy & Share Field Card

UN 3026 — Coumarin derivative pesticide, liquid, p
HAZMAT RADIO NOTE — UN 3026 Product: Coumarin derivative pesticide, liquid, poisonous Class 6 / Toxic / ERG 151 PPE: Level A or B required; SCBA mandatory; fully encapsulating chemical-resistant suit; double nitrile gloves; highly toxic via all routes of exposure ISOLATION: ERG 151: Isolate spill/leak area immediately for at least 50m in all directions; evacuate 800m downwind during fire; consider initial evacuation 100m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3026 — Coumarin derivative pesticide, liquid, poisonous Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Clear to pale yellow or amber liquid with mild to no odor. Viscosity varies by formulation. Liquid state at room temperature. Water Reactivity: No significant reaction with water, though may form emulsions or separate depending on formulation Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling. Avoid high-pressure water streams. PPE: Level A or B required; SCBA mandatory; fully encapsulating chemical-resistant suit; double nitrile gloves; highly toxic via all routes of exposure Isolation: ERG 151: Isolate spill/leak area immediately for at least 50m in all directions; evacuate 800m downwind during fire; consider initial evacuation 100m in all directions — Key Hazards — • Coumarin derivative pesticide formulations may be highly toxic by inhalation, ingestion or skin absorption. • Liquid contact can contaminate PPE and expose responders during doffing. • Fire or heating may release irritating, corrosive or toxic decomposition gases. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; avoid low areas where vapors may collect. • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/coumarin-derivative-pesticide-liquid-un-3026 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3026 Coumarin derivative pesticide, liquid, poisonous Cls6 ERG151 | allfirefighter.com/hazmat/un/coumarin-derivative-pesticide-liquid-un-3026SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/coumarin-derivative-pesticide-liquid-un-3026

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3026

UN 3026 is a coumarin derivative pesticide entry. The exact active ingredient and formulation must be confirmed from the SDS.

This entry is primarily toxic; flammability depends on the carrier solvent or formulation unless the shipping paper lists a flammable subsidiary risk.

Use SCBA and chemical-resistant protective clothing. Escalate to Level A when vapor, dust or liquid contact conditions are uncertain.

Many pesticide formulations can poison responders through dermal absorption or contaminate PPE during handling and decon.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.