☣️ UN 2022 • CLASS 6

UN 2022 — Cresylic acid

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2022 is Cresylic acid, a toxic/corrosive phenolic liquid assigned to ERG Guide 153. It can burn tissue, absorb through skin and produce toxic smoke in fire.

Hazard overview: TOXIC and CORROSIVE cresylic acid/phenolic liquid; inhalation, ingestion or skin contact may cause severe injury. Phenolic compounds can be absorbed through skin and contaminated clothing. Combustible liquid: may burn but does not ignite readily.

Response guidance: For a UN 2022 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff or dust spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2022 should emphasize toxic exposure routes, skin absorption, air monitoring, PPE selection, decontamination, runoff containment and ERG/SDS verification. Use ERG 153, SDS and local SOP.

Regulatory context: Cresylic acid is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Cresylic acid should be stored in tightly closed compatible containers in a secure toxic-material area with secondary containment, restricted access, ventilation and waste/decontamination planning according to SDS.

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UN 2022 Quick Details

UN 2022
Product name: Cresylic acid
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: Initial isolation 50m in all directions; protective action distance up to 300m downwind for large spills

Common Hazards of UN 2022

  • TOXIC and CORROSIVE cresylic acid/phenolic liquid; inhalation, ingestion or skin contact may cause severe injury.
  • Phenolic compounds can be absorbed through skin and contaminated clothing.
  • Combustible liquid: may burn but does not ignite readily.
  • Liquid can burn eyes, skin and respiratory tissue.
  • Fire may produce toxic phenolic smoke, carbon monoxide and irritating gases.
  • Runoff may be toxic, corrosive and environmentally harmful.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Colorless to yellowish or pinkish liquid with a characteristic phenolic, tar-like odor. May darken on exposure to air and light.

Also known asCresolTricresolMethylphenolCresylic acidMixed cresols
CAS Number1319-77-3
AppearanceColorless to yellowish or pinkish liquid with a characteristic phenolic, tar-like odor. May darken on exposure to air and light.
Flash Point81-86°C (178-187°F)
Boiling Point191-203°C (376-397°F)
Vapor Density3.7 (heavier than air)
Water ReactivitySlightly soluble in water; no significant violent reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2022

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic contamination.

PPE Requirements

⚠️ Level B minimum; SCBA and chemical-resistant suit required due to toxic vapors and severe skin contact hazard

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid skin contact.

Isolation & Evacuation

ERG 153: Initial isolation 50m in all directions; protective action distance up to 300m downwind for large spills
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2022 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing dust, vapor, fumes, mist or smoke and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, water reaction, vapor generation, dust spread or unknown product identity.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2022 — Cresylic acid
HAZMAT RADIO NOTE — UN 2022 Product: Cresylic acid Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA and chemical-resistant suit required due to toxic vapors and severe skin contact hazard ISOLATION: ERG 153: Initial isolation 50m in all directions; protective action distance up to 300m downwind for large spills ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2022 — Cresylic acid Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Colorless to yellowish or pinkish liquid with a characteristic phenolic, tar-like odor. May darken on exposure to air and light. Water Reactivity: Slightly soluble in water; no significant violent reaction Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic contamination. PPE: Level B minimum; SCBA and chemical-resistant suit required due to toxic vapors and severe skin contact hazard Isolation: ERG 153: Initial isolation 50m in all directions; protective action distance up to 300m downwind for large spills — Key Hazards — • TOXIC and CORROSIVE cresylic acid/phenolic liquid; inhalation, ingestion or skin contact may cause severe injury. • Phenolic compounds can be absorbed through skin and contaminated clothing. • Combustible liquid: may burn but does not ignite readily. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing dust, vapor, fumes, mist or smoke and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/cresylic-acid-un-2022 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2022 Cresylic acid Cls6 ERG153 | allfirefighter.com/hazmat/un/cresylic-acid-un-2022SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/cresylic-acid-un-2022

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2022

UN 2022 is Cresylic acid, a hazardous material assigned to ERG Guide 153.

It is combustible but does not ignite readily; phenolic toxicity and corrosivity are major hazards.

ERG Guide 153 applies to UN 2022 for initial isolation, protective actions and first response guidance.

TOXIC and CORROSIVE cresylic acid/phenolic liquid; inhalation, ingestion or skin contact may cause severe injury. Phenolic compounds can be absorbed through skin and contaminated clothing. Combustible liquid: may burn but does not ignite readily.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid skin contact.

These toxic organic materials can be absorbed through skin or contaminated clothing, so decontamination and chemical-resistant PPE are important.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.