☣️ UN 2872 • CLASS 6

UN 2872 — Dibromochloropropanes

Placard: Toxic. ERG Guide 159. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Dibromochloropropanes is an isomer/category shipping name for toxic halogenated propanes. Response should avoid assuming a single CAS-specific behavior and should verify the exact product.

Hazard overview: The key hazards are toxic vapor, skin absorption or contact, and corrosive halogen acid gases in fire. Because isomers can vary, the SDS is required for definitive guidance.

Response guidance: Isolate the spill, prevent entry to drains, and keep personnel out of vapor areas unless equipped with SCBA and chemical protection. Use foam, dry chemical, or CO2 as appropriate for fire exposure.

Firefighter training notes: Training should cover toxic dust/vapor control, decontamination, runoff containment, respiratory protection, and SDS-based exposure precautions for UN 2872.

Regulatory context: Confirm the exact shipping description, hazard class, packaging, SDS, and ERG 159; disposal and cleanup may require hazardous-waste controls.

Storage & handling: Store tightly closed in a dry, labeled area away from food, incompatible materials, and conditions that could spread dust, vapor, or contaminated runoff.

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UN 2872 Quick Details

UN 2872
Product name: Dibromochloropropanes
DOT Class: 6
Placard type: Toxic
ERG Guide: 159 (check current ERG)
Initial isolation: ERG 159: isolate spill/leak area immediately for 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate

Common Hazards of UN 2872

  • Toxic halogenated liquid category; inhalation, ingestion, or skin absorption can cause serious injury.
  • Vapors can irritate or damage respiratory tissues and may be heavier than air.
  • Liquid contact can injure skin and eyes and contaminate clothing.
  • Some isomers or formulations may burn, but they do not behave like simple gasoline-type liquids.
  • Fire can produce hydrogen bromide, hydrogen chloride, and other toxic corrosive gases.
  • Runoff can contaminate soil and waterways.
  • Exact isomer or mixture must be verified through SDS and shipping papers.

Chemical Identity & Physical Properties

Colorless to amber liquid with a pungent, chloroform-like odor. Dense liquid that sinks in water

Also known as1,2-Dibromo-3-chloropropaneDBCPNemagonFumazoneNematocide
CAS Number96-12-8
AppearanceColorless to amber liquid with a pungent, chloroform-like odor. Dense liquid that sinks in water.
Flash Point76C (170F)
Boiling Point195C (383F)
Vapor Density7.0 (much heavier than air)
Water ReactivityNo significant reaction with water; slightly soluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2872

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical, water spray for cooling

PPE Requirements

⚠️ Level B minimum with SCBA required; full chemical protective clothing for spill response due to severe inhalation and skin absorption hazards

Use SCBA with chemical-resistant suit, gloves, boots, and splash/face protection; Level A may be needed for unknown vapor concentrations.

Isolation & Evacuation

ERG 159: isolate spill/leak area immediately for 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 159).

First Actions for a UN 2872 Incident

  • Call 911 and the emergency response number shown on shipping papers or the SDS.
  • Keep unauthorized personnel away and prevent dust, vapor, or runoff from spreading.
  • Stay upwind, uphill, and upstream; avoid breathing dust, fumes, or fire gases.
  • Avoid all skin and eye contact with powder, liquid, solutions, or contaminated clothing.
  • Do not touch damaged containers or spilled material without chemical-resistant PPE.
  • Control runoff and keep material out of drains, soil, and waterways.
  • Use ERG guidance, SDS, shipping papers, and exposure monitoring before cleanup.
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📋 Copy & Share Field Card

UN 2872 — Dibromochloropropanes
HAZMAT RADIO NOTE — UN 2872 Product: Dibromochloropropanes Class 6 / Toxic / ERG 159 PPE: Level B minimum with SCBA required; full chemical protective clothing for spill response due to severe inhalation and skin absorption hazards ISOLATION: ERG 159: isolate spill/leak area immediately for 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2872 — Dibromochloropropanes Class: 6 | Placard: Toxic | ERG Guide: 159 Appearance: Colorless to amber liquid with a pungent, chloroform-like odor. Dense liquid that sinks in water. Water Reactivity: No significant reaction with water; slightly soluble Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling PPE: Level B minimum with SCBA required; full chemical protective clothing for spill response due to severe inhalation and skin absorption hazards Isolation: ERG 159: isolate spill/leak area immediately for 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate — Key Hazards — • Toxic halogenated liquid category; inhalation, ingestion, or skin absorption can cause serious injury. • Vapors can irritate or damage respiratory tissues and may be heavier than air. • Liquid contact can injure skin and eyes and contaminate clothing. — First Actions — • Call 911 and the emergency response number shown on shipping papers or the SDS. • Keep unauthorized personnel away and prevent dust, vapor, or runoff from spreading. • Stay upwind, uphill, and upstream; avoid breathing dust, fumes, or fire gases. • Avoid all skin and eye contact with powder, liquid, solutions, or contaminated clothing. SOURCE: allfirefighter.com/hazmat/un/dibromochloropropanes-un-2872 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2872 Dibromochloropropanes Cls6 ERG159 | allfirefighter.com/hazmat/un/dibromochloropropanes-un-2872SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/dibromochloropropanes-un-2872

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2872

Yes. Dibromochloropropanes should be treated as toxic by inhalation, ingestion, skin contact, or contaminated runoff unless the SDS says otherwise.

It is not primarily a flammable material unless the SDS or shipping description states otherwise, but fire can produce toxic fumes.

Prevent dust or vapor exposure and keep contaminated material out of drains and waterways.

Use respiratory protection with chemical-resistant clothing, gloves, boots, and eye/face protection.

Use water only if it will not spread contamination or create incompatible reactions; contain all runoff.

Verify the exact product, concentration, SDS, and shipping papers before cleanup.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.