☣️ UN 1655 • CLASS 6

UN 1655 — Nicotine preparation, solid, n.o.s.

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1655 is Nicotine preparation, solid, n.o.s., a highly toxic nicotine material assigned to ERG Guide 151. Skin absorption is a major responder concern, especially with liquids, solutions, salts or contaminated solids.

Hazard overview: UN 1655 presents toxic dermal absorption, ingestion, inhalation and contaminated-runoff hazards. Flammability depends on the formulation, but fire can produce toxic smoke and contaminated water.

Response guidance: For a UN 1655 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 151. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1655 should emphasize rapid dermal absorption, vapor/mist control, decontamination, contaminated clothing control and formulation-dependent flammability. Use ERG 151, SDS and local SOP.

Regulatory context: Nicotine preparation, solid, n.o.s. is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Nicotine preparation, solid, n.o.s. should be stored in tightly closed compatible containers in a secure, cool, well-ventilated toxic-material area away from heat, oxidizers, incompatible chemicals, food/feed and unauthorized access. Prevent leaks, contaminated packaging and skin-contact exposure.

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UN 1655 Quick Details

UN 1655
Product name: Nicotine preparation, solid, n.o.s.
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: Isolate spill area immediate 25m in all directions; for large spills isolate 50m and consider evacuation 300m downwind; treat as extremely toxic by all routes of exposure

Common Hazards of UN 1655

  • HIGHLY TOXIC nicotine material; inhalation, ingestion or skin absorption may be fatal.
  • Skin contact can be a major exposure route, especially with liquid, solution or contaminated solids.
  • Vapors or mist may be heavier than air and collect in low or confined areas when heated or released.
  • Combustibility depends on formulation; pure nicotine is combustible and many preparations may burn under fire conditions.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may spread toxic nicotine contamination.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Solid preparation containing nicotine; may appear as powder, granules, or impregnated material; color varies by formulation from tan to dark brown; may have characteristic tobacco-like odor.

Also known asNicotine3-(1-Methyl-2-pyrrolidinyl)pyridineBlack LeafNikotinNicotine salts
CAS Number54-11-5
AppearanceSolid preparation containing nicotine; may appear as powder, granules, or impregnated material; color varies by formulation from tan to dark brown; may have characteristic tobacco-like odor.
Flash PointVaries by formulation; pure nicotine: 95C (203F); solid preparations may be higher or not applicable depending on carrier material
Boiling Point247C (477F) for pure nicotine; not applicable for solid preparations
Vapor DensityNot applicable (solid preparation)
Water ReactivityNo significant reaction; nicotine is water-soluble but solid preparations typically dissolve rather than react
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1655

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination.

PPE Requirements

⚠️ Level A or B required; full chemical protective suit with SCBA; double gloves essential due to rapid dermal absorption; any skin contact can be fatal

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists. Level A or B may be needed depending on release size and concentration; prevent skin contact because nicotine can be absorbed rapidly through skin.

Isolation & Evacuation

ERG 151: Isolate spill area immediate 25m in all directions; for large spills isolate 50m and consider evacuation 300m downwind; treat as extremely toxic by all routes of exposure
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1655 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated liquid, powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 151, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1655 — Nicotine preparation, solid, n.o.s.
HAZMAT RADIO NOTE — UN 1655 Product: Nicotine preparation, solid, n.o.s. Class 6 / Toxic / ERG 151 PPE: Level A or B required; full chemical protective suit with SCBA; double gloves essential due to rapid dermal absorption; any skin contact can be fatal ISOLATION: ERG 151: Isolate spill area immediate 25m in all directions; for large spills isolate 50m and consider evacuation 300m downwind; treat as extremely toxic by all routes of exposure ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1655 — Nicotine preparation, solid, n.o.s. Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Solid preparation containing nicotine; may appear as powder, granules, or impregnated material; color varies by formulation from tan to dark brown; may have characteristic tobacco-like odor. Water Reactivity: No significant reaction; nicotine is water-soluble but solid preparations typically dissolve rather than react Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination. PPE: Level A or B required; full chemical protective suit with SCBA; double gloves essential due to rapid dermal absorption; any skin contact can be fatal Isolation: ERG 151: Isolate spill area immediate 25m in all directions; for large spills isolate 50m and consider evacuation 300m downwind; treat as extremely toxic by all routes of exposure — Key Hazards — • HIGHLY TOXIC nicotine material; inhalation, ingestion or skin absorption may be fatal. • Skin contact can be a major exposure route, especially with liquid, solution or contaminated solids. • Vapors or mist may be heavier than air and collect in low or confined areas when heated or released. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/nicotine-preparation-solid-n-un-1655 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1655 Nicotine preparation, solid, n.o.s. Cls6 ERG151 | allfirefighter.com/hazmat/un/nicotine-preparation-solid-n-un-1655SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nicotine-preparation-solid-n-un-1655

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1655

UN 1655 is Nicotine preparation, solid, n.o.s., a hazardous material assigned to ERG Guide 151.

It depends on the formulation. Pure nicotine is combustible, while some solid or aqueous preparations may not be readily flammable.

ERG Guide 151 applies to UN 1655 for initial isolation, protective actions and first response guidance.

UN 1655 presents toxic dermal absorption, ingestion, inhalation and contaminated-runoff hazards. Flammability depends on the formulation, but fire can produce toxic smoke and contaminated water.

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists. Level A or B may be needed depending on release size and concentration; prevent skin contact because nicotine can be absorbed rapidly through skin.

Nicotine can absorb through skin, especially from liquids, solutions or contaminated solids, so chemical PPE and decontamination matter.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.