☣️ UN 2307 • CLASS 6

UN 2307 — Nitro chlorobenzotrifluoride

Placard: Toxic. ERG Guide 152. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2307 is Nitro chlorobenzotrifluoride, a toxic nitroaromatic liquid assigned to ERG Guide 152. Fire can produce fluorinated/chlorinated toxic decomposition products.

Hazard overview: TOXIC nitroaromatic liquid; inhalation, ingestion or skin contact may cause serious injury. Combustible material: may burn but does not ignite readily. Vapors may be heavier than air and collect in low or confined areas when heated.

Response guidance: For a UN 2307 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 152. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2307 should emphasize toxic skin/vapor/dust exposure, contaminated clothing, toxic fire products, decontamination waste and runoff containment. Use ERG 152, SDS and local SOP.

Regulatory context: Nitro chlorobenzotrifluoride is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Nitro chlorobenzotrifluoride should be stored in tightly closed compatible containers in a secure toxic/corrosive-material area with secondary containment, restricted access, ventilation and waste/decontamination planning according to SDS.

Advertisement

UN 2307 Quick Details

UN 2307
Product name: Nitro chlorobenzotrifluoride
DOT Class: 6
Placard type: Toxic
ERG Guide: 152 (check current ERG)
Initial isolation: ERG 152: Initial isolation 50m all directions; protective action distance 300m downwind (day), 800m (night) for large spills

Common Hazards of UN 2307

  • TOXIC nitroaromatic liquid; inhalation, ingestion or skin contact may cause serious injury.
  • Combustible material: may burn but does not ignite readily.
  • Vapors may be heavier than air and collect in low or confined areas when heated.
  • Fire may produce hydrogen fluoride, hydrogen chloride where chlorinated, nitrogen oxides and toxic fluorinated smoke.
  • Runoff may carry toxic nitroaromatic/fluorinated contamination.
  • Skin contact and contaminated clothing can extend exposure.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Pale yellow to amber crystalline solid or liquid (melts around 34-36°C). Faint aromatic odor. Typically encountered as a molten liquid above room temperature.

Also known asNitro chlorobenzotrifluoride4-Chloro-3-nitrobenzotrifluoride1-Chloro-2-nitro-4-(trifluoromethyl)benzenep-Chloro-m-nitrobenzotrifluoride
CAS Number121-17-5
AppearancePale yellow to amber crystalline solid or liquid (melts around 34-36°C). Faint aromatic odor. Typically encountered as a molten liquid above room temperature.
Flash Point135°C (275°F)
Boiling Point222°C (432°F)
Vapor Density7.8 (much heavier than air)
Water ReactivityNo significant reaction with water, but insoluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2307

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic contamination.

PPE Requirements

⚠️ Level A recommended due to high toxicity; SCBA required; chemical-resistant suit; avoid all skin contact with molten material

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid all skin contact.

Isolation & Evacuation

ERG 152: Initial isolation 50m all directions; protective action distance 300m downwind (day), 800m (night) for large spills
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 152).

First Actions for a UN 2307 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Prevent contaminated liquid, dust, residues, runoff and decontamination waste from spreading.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
  • Use ERG Guide 152, shipping papers, SDS, air monitoring and incident command for protective actions.
Advertisement

📋 Copy & Share Field Card

UN 2307 — Nitro chlorobenzotrifluoride
HAZMAT RADIO NOTE — UN 2307 Product: Nitro chlorobenzotrifluoride Class 6 / Toxic / ERG 152 PPE: Level A recommended due to high toxicity; SCBA required; chemical-resistant suit; avoid all skin contact with molten material ISOLATION: ERG 152: Initial isolation 50m all directions; protective action distance 300m downwind (day), 800m (night) for large spills ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2307 — Nitro chlorobenzotrifluoride Class: 6 | Placard: Toxic | ERG Guide: 152 Appearance: Pale yellow to amber crystalline solid or liquid (melts around 34-36°C). Faint aromatic odor. Typically encountered as a molten liquid above room temperature. Water Reactivity: No significant reaction with water, but insoluble Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic contamination. PPE: Level A recommended due to high toxicity; SCBA required; chemical-resistant suit; avoid all skin contact with molten material Isolation: ERG 152: Initial isolation 50m all directions; protective action distance 300m downwind (day), 800m (night) for large spills — Key Hazards — • TOXIC nitroaromatic liquid; inhalation, ingestion or skin contact may cause serious injury. • Combustible material: may burn but does not ignite readily. • Vapors may be heavier than air and collect in low or confined areas when heated. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/nitro-chlorobenzotrifluoride-un-2307 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2307 Nitro chlorobenzotrifluoride Cls6 ERG152 | allfirefighter.com/hazmat/un/nitro-chlorobenzotrifluoride-un-2307SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitro-chlorobenzotrifluoride-un-2307

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2307

UN 2307 is Nitro chlorobenzotrifluoride, a hazardous material assigned to ERG Guide 152.

It is combustible but does not ignite readily; toxic exposure and toxic fire products are key hazards.

ERG Guide 152 applies to UN 2307 for initial isolation, protective actions and first response guidance.

TOXIC nitroaromatic liquid; inhalation, ingestion or skin contact may cause serious injury. Combustible material: may burn but does not ignite readily. Vapors may be heavier than air and collect in low or confined areas when heated.

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid all skin contact.

Toxic material may absorb through skin or contaminate clothing, so chemical-resistant PPE and decontamination are important.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.