☣️ UN 3270 • CLASS 4

UN 3270 — Nitrocellulose membrane filters

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3270 is Nitrocellulose membrane filters, a flammable nitrocellulose membrane entry assigned to ERG Guide 133. Dryness, friction and re-ignition are key hazards.

Hazard overview: FLAMMABLE nitrocellulose membrane material; dry filters can ignite from heat, sparks or friction. May burn rapidly with flare-burning behavior. Dry sheets, discs or dust can spread fire quickly; wetted material is generally less ignitable.

Response guidance: For UN 3270, isolate the area, avoid exposure and use SCBA where vapor, dust, smoke or fire is present. Verify exact controls with SDS and ERG 133.

Firefighter training notes: Training for UN 3270 should emphasize product verification, SCBA use, vapor/dust monitoring, fire behavior, decontamination and runoff control. Use ERG 133, SDS and local SOP.

Regulatory context: Nitrocellulose membrane filters is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, composition, concentration and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Nitrocellulose membrane filters should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

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UN 3270 Quick Details

UN 3270
Product name: Nitrocellulose membrane filters
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: isolate spill 25m all directions; if fire isolate 800m all directions, evacuate 800m downwind

Common Hazards of UN 3270

  • FLAMMABLE nitrocellulose membrane material; dry filters can ignite from heat, sparks or friction.
  • May burn rapidly with flare-burning behavior.
  • Dry sheets, discs or dust can spread fire quickly; wetted material is generally less ignitable.
  • Heating or fire may produce nitrogen oxides and irritating/toxic smoke.
  • May re-ignite if hot or partially burned material remains.
  • Runoff may carry contaminated cellulose nitrate residue.
  • Condition, moisture content and packaging must be verified.

Chemical Identity & Physical Properties

White to slightly yellow solid membrane or filter material, odorless or slight chemical odor. Typically supplied as thin sheets or discs in dry or wetted condition.

Also known asCellulose nitrateNitrated celluloseCollodion cottonPyroxylinGuncotton (high nitrogen content)NC membranes
CAS Number9004-70-0
AppearanceWhite to slightly yellow solid membrane or filter material, odorless or slight chemical odor. Typically supplied as thin sheets or discs in dry or wetted condition.
Flash PointNot applicable (self-reactive solid, ignites readily at 160-170C)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water; wetting with water increases stability and reduces fire risk
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3270

Extinguishing Media

Use water spray/fog for cooling and to keep material wetted where safe. Dry chemical or CO2 may work on small fires; monitor for re-ignition.

PPE Requirements

⚠️ Level C minimum for handling; Level B with SCBA if fire or decomposition occurring; fire-resistant clothing for fire response

Use positive-pressure SCBA for vapor, dust, smoke, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 133: isolate spill 25m all directions; if fire isolate 800m all directions, evacuate 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 3270 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated liquid, dust, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 133, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3270 — Nitrocellulose membrane filters
HAZMAT RADIO NOTE — UN 3270 Product: Nitrocellulose membrane filters Class 4 / Flammable Solid / ERG 133 PPE: Level C minimum for handling; Level B with SCBA if fire or decomposition occurring; fire-resistant clothing for fire response ISOLATION: ERG 133: isolate spill 25m all directions; if fire isolate 800m all directions, evacuate 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3270 — Nitrocellulose membrane filters Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: White to slightly yellow solid membrane or filter material, odorless or slight chemical odor. Typically supplied as thin sheets or discs in dry or wetted condition. Water Reactivity: No significant reaction with water; wetting with water increases stability and reduces fire risk Extinguishing: Use water spray/fog for cooling and to keep material wetted where safe. Dry chemical or CO2 may work on small fires; monitor for re-ignition. PPE: Level C minimum for handling; Level B with SCBA if fire or decomposition occurring; fire-resistant clothing for fire response Isolation: ERG 133: isolate spill 25m all directions; if fire isolate 800m all directions, evacuate 800m downwind — Key Hazards — • FLAMMABLE nitrocellulose membrane material; dry filters can ignite from heat, sparks or friction. • May burn rapidly with flare-burning behavior. • Dry sheets, discs or dust can spread fire quickly; wetted material is generally less ignitable. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/nitrocellulose-membrane-filters-un-3270 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3270 Nitrocellulose membrane filters Cls4 ERG133 | allfirefighter.com/hazmat/un/nitrocellulose-membrane-filters-un-3270SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrocellulose-membrane-filters-un-3270

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3270

UN 3270 is Nitrocellulose membrane filters, assigned to ERG Guide 133.

Flammability depends on exact composition and package condition; verify SDS and shipping papers.

FLAMMABLE nitrocellulose membrane material; dry filters can ignite from heat, sparks or friction. May burn rapidly with flare-burning behavior. Dry sheets, discs or dust can spread fire quickly; wetted material is generally less ignitable.

Use positive-pressure SCBA for vapor, dust, smoke, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and protective clothing.

Use water spray/fog for cooling and to keep material wetted where safe. Dry chemical or CO2 may work on small fires; monitor for re-ignition.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.