☣️ UN 2660 • CLASS 6

UN 2660 — Nitrotoluidines (mono)

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2660 is Nitrotoluidines (mono), a toxic aromatic amine entry assigned to ERG Guide 153. Skin absorption and exact form/isomer review are important.

Hazard overview: TOXIC aromatic amine material; inhalation, ingestion or skin absorption may cause serious injury. Skin contact and contaminated clothing are major exposure concerns. Combustible solid/liquid: may burn but does not ignite readily.

Response guidance: For UN 2660, isolate the area, avoid skin contact and use SCBA where dust, vapor, mist or fire is present. Prevent spread of contaminated runoff, cool containers from protection and verify controls with SDS and ERG 153.

Firefighter training notes: Training for UN 2660 should emphasize toxic exposure routes, skin absorption, SCBA use, dust/vapor control, decontamination, runoff containment and SDS verification. Use ERG 153, SDS and local SOP.

Regulatory context: Nitrotoluidines (mono) is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Nitrotoluidines (mono) should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

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UN 2660 Quick Details

UN 2660
Product name: Nitrotoluidines (mono)
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation

Common Hazards of UN 2660

  • TOXIC aromatic amine material; inhalation, ingestion or skin absorption may cause serious injury.
  • Skin contact and contaminated clothing are major exposure concerns.
  • Combustible solid/liquid: may burn but does not ignite readily.
  • Heating or fire may produce nitrogen oxides and toxic aromatic amine smoke.
  • Molten material, if present, can cause thermal and toxic contact exposure.
  • Runoff may carry toxic amine contamination.
  • Exact isomer/form and physical state should be verified from SDS.

Chemical Identity & Physical Properties

Yellow to orange-brown crystalline solid or powder at room temperature. May have a slight aromatic odor. Toxic by all routes of exposure.

Also known asmononitrotoluidinesnitrotoluidine isomersaminonitrotoluenenitromethylaniline
AppearanceYellow to orange-brown crystalline solid or powder at room temperature. May have a slight aromatic odor. Toxic by all routes of exposure.
Flash PointNot applicable (combustible solid)
Boiling PointVaries by isomer, typically 250-280C (482-536F)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water, but slightly soluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2660

Extinguishing Media

Use dry chemical, CO2, alcohol-resistant foam or water spray as compatible with fire size. Cool containers from protection and contain toxic/corrosive runoff.

PPE Requirements

⚠️ Level B minimum; SCBA required; impervious gloves and suit to prevent skin contact; highly toxic material

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2660 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated dust, liquid, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 153, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2660 — Nitrotoluidines (mono)
HAZMAT RADIO NOTE — UN 2660 Product: Nitrotoluidines (mono) Class 6 / Toxic / ERG 153 PPE: Level B minimum; SCBA required; impervious gloves and suit to prevent skin contact; highly toxic material ISOLATION: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2660 — Nitrotoluidines (mono) Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Yellow to orange-brown crystalline solid or powder at room temperature. May have a slight aromatic odor. Toxic by all routes of exposure. Water Reactivity: No significant reaction with water, but slightly soluble Extinguishing: Use dry chemical, CO2, alcohol-resistant foam or water spray as compatible with fire size. Cool containers from protection and contain toxic/corrosive runoff. PPE: Level B minimum; SCBA required; impervious gloves and suit to prevent skin contact; highly toxic material Isolation: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation — Key Hazards — • TOXIC aromatic amine material; inhalation, ingestion or skin absorption may cause serious injury. • Skin contact and contaminated clothing are major exposure concerns. • Combustible solid/liquid: may burn but does not ignite readily. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/nitrotoluidines-un-2660 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2660 Nitrotoluidines (mono) Cls6 ERG153 | allfirefighter.com/hazmat/un/nitrotoluidines-un-2660SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrotoluidines-un-2660

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2660

UN 2660 is Nitrotoluidines (mono), assigned to ERG Guide 153.

It is combustible but does not ignite readily; toxic exposure and fire decomposition products are the main hazards.

TOXIC aromatic amine material; inhalation, ingestion or skin absorption may cause serious injury. Skin contact and contaminated clothing are major exposure concerns. Combustible solid/liquid: may burn but does not ignite readily.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use dry chemical, CO2, alcohol-resistant foam or water spray as compatible with fire size. Cool containers from protection and contain toxic/corrosive runoff.

Toxic material can contaminate clothing, tools and runoff, extending exposure beyond the original spill area.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.