☣️ UN 3019 • CLASS 6

UN 3019 — Organotin pesticide, liquid, poisonous, flammable

Placard: Toxic. ERG Guide 131. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Organotin pesticide, liquid, poisonous, flammable is a liquid pesticide formulation assigned to UN 3019. It should be treated as a toxic pesticide product until the active ingredient, carrier solvent and concentration are confirmed from shipping papers and the SDS.

Hazard overview: Organotin pesticides may cause serious systemic toxicity and persistent contamination; avoid all contact with liquid and vapors.

Response guidance: For UN 3019, isolate the release, remove ignition sources, stay upwind and keep runoff out of drains. Use alcohol-resistant foam, dry chemical or CO2 for fire control, with water spray only for cooling exposed containers when safe. Confirm the exact organotin pesticide formulation from shipping papers and SDS before close approach.

Firefighter training notes: Train responders to treat UN 3019 as a toxic pesticide release, verify the exact product, control runoff and avoid skin contact during rescue, containment and decon.

Regulatory context: UN 3019 is regulated for transport as a hazardous pesticide entry. Product labels, shipping papers, SDS and local environmental reporting rules should guide final actions.

Storage & handling: Store UN 3019 away from food, feed, drains, ignition sources where applicable and incompatible chemicals. Keep containers closed, labeled and protected from heat or physical damage.

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UN 3019 Quick Details

UN 3019
Product name: Organotin pesticide, liquid, poisonous, flammable
DOT Class: 6
Placard type: Toxic
ERG Guide: 131 (check current ERG)
Initial isolation: ERG 131: isolate spill/leak area immediately 50m (150 ft) all directions; if tank/rail car involved in fire isolate 800m (1/2 mile) all directions and consider evacuation

Common Hazards of UN 3019

  • Organotin pesticide formulations may be fatal if inhaled, ingested or absorbed through skin.
  • Flammable solvent vapors may ignite from heat, sparks, flames or static discharge.
  • Vapors may form explosive mixtures with air and travel to ignition sources.
  • Skin or eye contact may cause irritation, burns or systemic poisoning.
  • Fire can produce toxic pesticide decomposition products and corrosive smoke.
  • Runoff can spread contamination and harm waterways.
  • Exact toxicity, flash point and solvent behavior depend on the shipped formulation.

Chemical Identity & Physical Properties

Liquid, color and odor vary depending on specific organotin compound and formulation. Typically pale yellow to amber liquid with mild to pungent organic odor. Product-specific appearance and odor should not be used as the only identification method.

Also known asOrganotin compound pesticideTributyltin pesticideTriphenyltin pesticideOrganostannane pesticide
AppearanceLiquid, color and odor vary depending on specific organotin compound and formulation. Typically pale yellow to amber liquid with mild to pungent organic odor.
Flash Point23-61C (73-142F) typical range for flammable organotin pesticide solutions
Boiling Point150-300C (302-572F) depending on specific organotin compound and solvent
Vapor DensityGreater than 1 (heavier than air)
Water ReactivityNo significant reaction with water, though may hydrolyze slowly in aqueous environments
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3019

Extinguishing Media

Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only

PPE Requirements

⚠️ Level B minimum with full face SCBA; Level A if vapor concentrations unknown or release is significant; nitrile or neoprene chemical-resistant gloves

Use positive-pressure SCBA and chemical-resistant protective clothing suitable for pesticide liquids. Gloves, boots and suit material should be selected from the SDS because permeation varies by active ingredient and solvent.

Isolation & Evacuation

ERG 131: isolate spill/leak area immediately 50m (150 ft) all directions; if tank/rail car involved in fire isolate 800m (1/2 mile) all directions and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 131).

First Actions for a UN 3019 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Eliminate ignition sources; use non-sparking tools and control traffic around the spill.
  • Keep unauthorized personnel away and stay upwind, uphill and upstream.
  • Avoid breathing vapors and prevent liquid contact with skin, eyes and clothing.
  • Do not enter low areas, drains or confined spaces unless trained and equipped.
  • Use ERG 131, SDS, shipping papers and monitoring to set isolation and evacuation distances.
  • Contain runoff only if it can be done safely with proper PPE.
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📋 Copy & Share Field Card

UN 3019 — Organotin pesticide, liquid, poisonous,
HAZMAT RADIO NOTE — UN 3019 Product: Organotin pesticide, liquid, poisonous, flammable Class 6 / Toxic / ERG 131 PPE: Level B minimum with full face SCBA; Level A if vapor concentrations unknown or release is significant; nitrile or neoprene chemical-resistant gloves ISOLATION: ERG 131: isolate spill/leak area immediately 50m (150 ft) all directions; if tank/rail car involved in fire isolate 800m (1/2 mile) all directions and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3019 — Organotin pesticide, liquid, poisonous, flammable Class: 6 | Placard: Toxic | ERG Guide: 131 Appearance: Liquid, color and odor vary depending on specific organotin compound and formulation. Typically pale yellow to amber liquid with mild to pungent organic odor. Water Reactivity: No significant reaction with water, though may hydrolyze slowly in aqueous environments Extinguishing: Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only PPE: Level B minimum with full face SCBA; Level A if vapor concentrations unknown or release is significant; nitrile or neoprene chemical-resistant gloves Isolation: ERG 131: isolate spill/leak area immediately 50m (150 ft) all directions; if tank/rail car involved in fire isolate 800m (1/2 mile) all directions and consider evacuation — Key Hazards — • Organotin pesticide formulations may be fatal if inhaled, ingested or absorbed through skin. • Flammable solvent vapors may ignite from heat, sparks, flames or static discharge. • Vapors may form explosive mixtures with air and travel to ignition sources. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Eliminate ignition sources; use non-sparking tools and control traffic around the spill. • Keep unauthorized personnel away and stay upwind, uphill and upstream. • Avoid breathing vapors and prevent liquid contact with skin, eyes and clothing. SOURCE: allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3019 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3019 Organotin pesticide, liquid, poisonous, flammable Cls6 ERG131 | allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3019SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3019

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3019

Yes. This entry includes a flammable liquid carrier, so vapors may ignite and flash back to the spill.

Yes. It may be harmful or fatal by inhalation, ingestion or skin absorption, depending on the formulation.

Use positive-pressure SCBA and chemical-resistant clothing. Level A or B may be required based on vapor level and product identity.

Alcohol-resistant foam, dry chemical or CO2 are typical choices; use water spray mainly for cooling exposed containers.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.