☣️ UN 3020 • CLASS 6

UN 3020 — Organotin pesticide, liquid, poisonous

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Organotin pesticide, liquid, poisonous is a liquid pesticide formulation assigned to UN 3020. It should be treated as a toxic pesticide product until the active ingredient, carrier solvent and concentration are confirmed from shipping papers and the SDS.

Hazard overview: The main concern with UN 3020 is toxic exposure from the pesticide formulation. Dermal absorption, inhalation of vapors or dust, ingestion, contaminated runoff and toxic fire gases are the response priorities.

Response guidance: For UN 3020, isolate the spill area, keep personnel upwind and avoid all skin contact. Use absorbent or containment methods compatible with the formulation and keep contaminated runoff out of drains. Fire control should focus on exposed packaging and the carrier solvent if present; verify the SDS before choosing water or foam.

Firefighter training notes: Train responders to treat UN 3020 as a toxic pesticide release, verify the exact product, control runoff and avoid skin contact during rescue, containment and decon.

Regulatory context: UN 3020 is regulated for transport as a hazardous pesticide entry. Product labels, shipping papers, SDS and local environmental reporting rules should guide final actions.

Storage & handling: Store UN 3020 away from food, feed, drains, ignition sources where applicable and incompatible chemicals. Keep containers closed, labeled and protected from heat or physical damage.

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UN 3020 Quick Details

UN 3020
Product name: Organotin pesticide, liquid, poisonous
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: Initial isolation 50m all directions; protective action distance 300m downwind (day), 900m (night) for small spills

Common Hazards of UN 3020

  • Organotin pesticide formulations may be highly toxic by inhalation, ingestion or skin absorption.
  • Liquid contact can contaminate PPE and expose responders during doffing.
  • Fire or heating may release irritating, corrosive or toxic decomposition gases.
  • Containers may rupture when heated even when the product itself is not readily flammable.
  • Runoff from spill control or firefighting can carry pesticide contamination into waterways.
  • Some formulations contain solvents or surfactants that change vapor, foam and cleanup behavior.
  • Exact product identity and concentration must be verified from SDS and shipping papers.

Chemical Identity & Physical Properties

Liquid of variable color (often colorless to pale yellow), may have mild to pungent odor depending on specific organotin compound. Room temperature liquid pesticide formulation. Product-specific appearance and odor should not be used as the only identification method.

Also known asOrganotin compound pesticideTin-organic pesticide solutionTributyltin compoundsTriphenyltin formulations
AppearanceLiquid of variable color (often colorless to pale yellow), may have mild to pungent odor depending on specific organotin compound. Room temperature liquid pesticide formulation.
Flash PointVariable, typically 23-61C (73-142F) depending on solvent carrier
Boiling PointVariable, typically 100-300C (212-572F) depending on formulation
Vapor DensityHeavier than air (typically >3), vapors will concentrate in low areas
Water ReactivityNo violent reaction but generally immiscible; may hydrolyze slowly releasing toxic vapors
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3020

Extinguishing Media

Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only

PPE Requirements

⚠️ Level A or B required; full face SCBA mandatory; chemical-resistant suit; butyl rubber gloves; highly toxic by all routes of exposure

Use positive-pressure SCBA and chemical-resistant protective clothing suitable for pesticide liquids. Gloves, boots and suit material should be selected from the SDS because permeation varies by active ingredient and solvent.

Isolation & Evacuation

ERG 153: Initial isolation 50m all directions; protective action distance 300m downwind (day), 900m (night) for small spills
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 3020 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; avoid low areas where vapors may collect.
  • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact.
  • Do not touch damaged containers or spilled material without appropriate PPE.
  • Ventilate confined spaces only when trained, equipped and authorized.
  • Use ERG 153, SDS, shipping papers and monitoring to confirm product hazards before close approach.
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📋 Copy & Share Field Card

UN 3020 — Organotin pesticide, liquid, poisonous
HAZMAT RADIO NOTE — UN 3020 Product: Organotin pesticide, liquid, poisonous Class 6 / Toxic / ERG 153 PPE: Level A or B required; full face SCBA mandatory; chemical-resistant suit; butyl rubber gloves; highly toxic by all routes of exposure ISOLATION: ERG 153: Initial isolation 50m all directions; protective action distance 300m downwind (day), 900m (night) for small spills ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3020 — Organotin pesticide, liquid, poisonous Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Liquid of variable color (often colorless to pale yellow), may have mild to pungent odor depending on specific organotin compound. Room temperature liquid pesticide formulation. Water Reactivity: No violent reaction but generally immiscible; may hydrolyze slowly releasing toxic vapors Extinguishing: Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only PPE: Level A or B required; full face SCBA mandatory; chemical-resistant suit; butyl rubber gloves; highly toxic by all routes of exposure Isolation: ERG 153: Initial isolation 50m all directions; protective action distance 300m downwind (day), 900m (night) for small spills — Key Hazards — • Organotin pesticide formulations may be highly toxic by inhalation, ingestion or skin absorption. • Liquid contact can contaminate PPE and expose responders during doffing. • Fire or heating may release irritating, corrosive or toxic decomposition gases. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; avoid low areas where vapors may collect. • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3020 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3020 Organotin pesticide, liquid, poisonous Cls6 ERG153 | allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3020SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/organotin-pesticide-liquid-poisonous-un-3020

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3020

UN 3020 is a organotin pesticide entry. The exact active ingredient and formulation must be confirmed from the SDS.

This entry is primarily toxic; flammability depends on the carrier solvent or formulation unless the shipping paper lists a flammable subsidiary risk.

Use SCBA and chemical-resistant protective clothing. Escalate to Level A when vapor, dust or liquid contact conditions are uncertain.

Many pesticide formulations can poison responders through dermal absorption or contaminate PPE during handling and decon.

Isolate the area, keep personnel upwind, prevent runoff and use product-specific SDS guidance for containment and cleanup.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.