☣️ UN 2588 • CLASS 6

UN 2588 — Pesticide, solid, poisonous, n.o.s.

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2588 is a broad entry for poisonous solid pesticides not otherwise specified. The exact active ingredient and formulation control the real exposure and cleanup hazards.

Hazard overview: This entry should not be treated as one chemical. Dust, contaminated packaging or fire smoke may be toxic, and runoff can carry pesticide residues into soil or waterways.

Response guidance: Identify the product from labels, shipping papers and SDS before committing crews. Isolate dust, keep material out of drains, avoid skin contact and use ERG 151 only as initial guidance until product-specific data is confirmed.

Firefighter training notes: Train responders to treat n.o.s. pesticide entries as variable toxic products. Emphasize label/SDS identification, dust containment, decon and environmental protection.

Regulatory context: UN 2588 is Pesticide, solid, poisonous, n.o.s., Class 6.1. Regulatory handling depends on the active ingredient, formulation and package markings.

Storage & handling: Store according to the pesticide label in a secure, dry, ventilated area. Keep away from food, feed, drains, incompatible chemicals and unauthorized access.

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UN 2588 Quick Details

UN 2588
Product name: Pesticide, solid, poisonous, n.o.s.
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: Use ERG 151 as initial guidance, but final isolation depends on active ingredient, quantity, dust generation, wind and label/SDS instructions.

Common Hazards of UN 2588

  • Broad toxic pesticide solid category; exact active ingredient determines the primary health hazard.
  • Poisonous by inhalation of dust, ingestion or skin contact; some products may be readily absorbed through skin.
  • Fire may produce toxic pesticide decomposition gases and irritating smoke.
  • Dust can contaminate clothing, equipment and response areas.
  • Runoff from spills or fire control can contaminate soil, drains and waterways.
  • Some formulations may be combustible or contain carriers that burn.
  • Containers may rupture or release toxic dust when heated or damaged.

Chemical Identity & Physical Properties

Physical form varies by pesticide product and may include powders, granules, pellets or treated solids. Odor, color and solubility are formulation-dependent.

AppearanceVaries widely - typically a powder, granules, or crystalline solid ranging from white to colored depending on active ingredient and formulation. Odor varies from odorless to characteristic chemical smell.
Flash PointNot applicable (solid pesticide, combustibility depends on specific formulation)
Boiling PointNot applicable (solid material, may decompose before boiling)
Vapor DensityNot applicable (solid material at room temperature)
Water ReactivityVaries by active ingredient and formulation; do not assume water compatibility without SDS and label information.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2588

Extinguishing Media

Use extinguishing agent suitable for the product and packaging; dry chemical, CO2, foam or water spray may be appropriate after SDS review.

PPE Requirements

⚠️ SCBA and chemical protective clothing are required for unknown pesticide dust or fire smoke; prevent skin absorption and cross-contamination.

Use SCBA for dust, smoke or unknown atmospheres. Chemical protective clothing, gloves and boots should be selected for the active ingredient and carrier.

Isolation & Evacuation

Use ERG 151 as initial guidance, but final isolation depends on active ingredient, quantity, dust generation, wind and label/SDS instructions.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 2588 Incident

  • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings.
  • Keep unauthorized personnel away and establish hot, warm and cold zones before entry.
  • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect.
  • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact.
  • Do not touch damaged packages or containers unless properly trained and wearing suitable chemical PPE.
  • Ventilate confined spaces only after atmospheric monitoring and only with trained, equipped personnel.
  • Use ERG Guide 151, SDS, shipping papers and monitoring results for isolation, PPE and fire-control decisions.
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📋 Copy & Share Field Card

UN 2588 — Pesticide, solid, poisonous, n.o.s.
HAZMAT RADIO NOTE — UN 2588 Product: Pesticide, solid, poisonous, n.o.s. Class 6 / Toxic / ERG 151 PPE: SCBA and chemical protective clothing are required for unknown pesticide dust or fire smoke; prevent skin absorption and cross-contamination. ISOLATION: Use ERG 151 as initial guidance, but final isolation depends on active ingredient, quantity, dust generation, wind and label/SDS instructions. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2588 — Pesticide, solid, poisonous, n.o.s. Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Varies widely - typically a powder, granules, or crystalline solid ranging from white to colored depending on active ingredient and formulation. Odor varies from odorless to characteristic chemical smell. Water Reactivity: Varies by active ingredient and formulation; do not assume water compatibility without SDS and label information. Extinguishing: Use extinguishing agent suitable for the product and packaging; dry chemical, CO2, foam or water spray may be appropriate after SDS review. PPE: SCBA and chemical protective clothing are required for unknown pesticide dust or fire smoke; prevent skin absorption and cross-contamination. Isolation: Use ERG 151 as initial guidance, but final isolation depends on active ingredient, quantity, dust generation, wind and label/SDS instructions. — Key Hazards — • Broad toxic pesticide solid category; exact active ingredient determines the primary health hazard. • Poisonous by inhalation of dust, ingestion or skin contact; some products may be readily absorbed through skin. • Fire may produce toxic pesticide decomposition gases and irritating smoke. — First Actions — • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings. • Keep unauthorized personnel away and establish hot, warm and cold zones before entry. • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect. • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/pesticide-solid-poisonous-n-un-2588 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2588 Pesticide, solid, poisonous, n.o.s. Cls6 ERG151 | allfirefighter.com/hazmat/un/pesticide-solid-poisonous-n-un-2588SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/pesticide-solid-poisonous-n-un-2588

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2588

It covers pesticide solids not listed under a more specific UN entry, so the active ingredient must be verified.

Toxic exposure from dust, skin contact, ingestion or fire smoke is the main concern.

Do not assume it is safe. Water compatibility and runoff risk depend on the actual pesticide formulation.

The pesticide label, SDS and shipping papers are essential because they identify the active ingredient and controls.

Pesticide residues can contaminate waterways, soil and response equipment.

SCBA and chemical protective clothing are prudent until the exact pesticide and exposure route are confirmed.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.