☣️ UN 1672 • CLASS 6

UN 1672 — Phenylcarbylamine chloride

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1672 is Phenylcarbylamine chloride, a toxic corrosive material assigned to ERG Guide 151. Moisture or water contact can release corrosive and toxic fumes, making dry control and air monitoring important.

Hazard overview: UN 1672 presents toxic inhalation, corrosive fume and water-reactivity hazards. Vapors can collect in low areas, and runoff may spread corrosive toxic contamination.

Response guidance: For a UN 1672 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 151. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1672 should emphasize water-reactive toxic/corrosive fumes, dry-agent selection, vapor control, decontamination and strict entry control. Use ERG 151, SDS and hazmat SOP.

Regulatory context: Phenylcarbylamine chloride is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Phenylcarbylamine chloride should be stored in tightly closed compatible containers in a cool, dry, well-ventilated secure area away from water, moisture, bases where incompatible, oxidizers, heat and unauthorized access. Protect containers from corrosion, leaks and impact.

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UN 1672 Quick Details

UN 1672
Product name: Phenylcarbylamine chloride
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate spill 25-50m all directions; evacuate 100m downwind during spill; if fire, isolate 800m in all directions

Common Hazards of UN 1672

  • TOXIC and CORROSIVE; inhalation, ingestion or skin/eye contact may cause severe injury.
  • Water or moist air may release toxic and corrosive fumes.
  • Reaction with water may generate heat and dense irritating vapor.
  • Vapors are heavier than air and may collect in low or confined areas.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may spread toxic and corrosive contamination.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a pungent, irritating odor. Lachrymatory (causes tearing). Corrosive and highly toxic.

Also known asPhenyl isocyanide dichlorideBenzenecarbonitrile dichloridePhenyl carbylamine dichlorideDichlorophenylmethylenimine
CAS Number622-44-6
AppearanceColorless to pale yellow liquid with a pungent, irritating odor. Lachrymatory (causes tearing). Corrosive and highly toxic.
Flash PointNot readily available; handle as flammable liquid
Boiling PointApproximately 195-200°C (383-392°F) with decomposition
Vapor DensityHeavier than air (vapor density >1)
Water ReactivityReacts with water and moisture, producing toxic and corrosive fumes including HCl
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1672

Extinguishing Media

Use dry chemical, CO2, dry sand, soda ash or other compatible dry media when directed by incident command. Avoid applying water or foam directly to product because moisture can release toxic and corrosive fumes.

PPE Requirements

⚠️ Level A required; full encapsulating suit with SCBA; avoid all skin and eye contact; highly toxic by all routes

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists for vapor, fume, liquid or unknown exposure. Level A may be needed for close entry because toxic and corrosive fumes are possible.

Isolation & Evacuation

ERG 151: isolate spill 25-50m all directions; evacuate 100m downwind during spill; if fire, isolate 800m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1672 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Keep water and moisture away from released product unless incident command confirms a compatible cooling or control use.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated liquid, powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 151, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1672 — Phenylcarbylamine chloride
HAZMAT RADIO NOTE — UN 1672 Product: Phenylcarbylamine chloride Class 6 / Toxic / ERG 151 PPE: Level A required; full encapsulating suit with SCBA; avoid all skin and eye contact; highly toxic by all routes ISOLATION: ERG 151: isolate spill 25-50m all directions; evacuate 100m downwind during spill; if fire, isolate 800m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1672 — Phenylcarbylamine chloride Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Colorless to pale yellow liquid with a pungent, irritating odor. Lachrymatory (causes tearing). Corrosive and highly toxic. Water Reactivity: Reacts with water and moisture, producing toxic and corrosive fumes including HCl Extinguishing: Use dry chemical, CO2, dry sand, soda ash or other compatible dry media when directed by incident command. Avoid applying water or foam directly to product because moisture can release toxic and corrosive fumes. PPE: Level A required; full encapsulating suit with SCBA; avoid all skin and eye contact; highly toxic by all routes Isolation: ERG 151: isolate spill 25-50m all directions; evacuate 100m downwind during spill; if fire, isolate 800m in all directions — Key Hazards — • TOXIC and CORROSIVE; inhalation, ingestion or skin/eye contact may cause severe injury. • Water or moist air may release toxic and corrosive fumes. • Reaction with water may generate heat and dense irritating vapor. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/phenylcarbylamine-chloride-un-1672 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1672 Phenylcarbylamine chloride Cls6 ERG151 | allfirefighter.com/hazmat/un/phenylcarbylamine-chloride-un-1672SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/phenylcarbylamine-chloride-un-1672

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1672

UN 1672 is Phenylcarbylamine chloride, a hazardous material assigned to ERG Guide 151.

No. It is not normally flammable, but heat or moisture can produce toxic and corrosive decomposition products.

ERG Guide 151 applies to UN 1672 for initial isolation, protective actions and first response guidance.

UN 1672 presents toxic inhalation, corrosive fume and water-reactivity hazards. Vapors can collect in low areas, and runoff may spread corrosive toxic contamination.

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists for vapor, fume, liquid or unknown exposure. Level A may be needed for close entry because toxic and corrosive fumes are possible.

Do not apply water directly to the material unless incident command and SDS confirm a safe use, because moisture can release heat, toxic fumes and corrosive gases.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.