☣️ UN 1674 • CLASS 6

UN 1674 — Phenylmercuric acetate

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1674 is Phenylmercuric acetate, a toxic mercury compound assigned to ERG Guide 151. Dust, solution and runoff contamination are the major responder concerns.

Hazard overview: UN 1674 presents toxic mercury dust, ingestion, skin contact and contaminated-runoff hazards. Heating or fire may release mercury-containing fumes, and dry powder can contaminate clothing and equipment.

Response guidance: For a UN 1674 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 151. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1674 should emphasize mercury compound toxicity, dust or solution contamination, SCBA use, runoff containment, decontamination and waste-control coordination. Use ERG 151, SDS and local SOP.

Regulatory context: Phenylmercuric acetate is regulated as a toxic mercury hazardous material. Transportation, occupational exposure, spill reporting, waste handling, storage and environmental controls may vary by compound, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Phenylmercuric acetate should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated toxic-material area away from food, incompatible chemicals, heat and unauthorized access. Prevent dust release, solution leaks and mercury-contaminated runoff.

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UN 1674 Quick Details

UN 1674
Product name: Phenylmercuric acetate
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate spill/leak area immediately for at least 25-50m in all directions; if large spill isolate 100m; evacuate downwind areas if airborne dust

Common Hazards of UN 1674

  • HIGHLY TOXIC mercury compound; may be harmful or fatal if inhaled, ingested or absorbed through skin.
  • Dust or solution can contaminate clothing, tools, equipment and runoff.
  • Fire or heating may produce toxic mercury fumes and irritating decomposition products.
  • Runoff may pollute waterways and create persistent contamination.
  • Containers may rupture or fail when heated.
  • Specific toxicity, solubility and reactivity depend on the exact mercury compound.
  • Avoid skin contact and prevent dust from becoming airborne.

Chemical Identity & Physical Properties

White to cream-colored crystalline powder or prisms. Practically odorless. Solid at room temperature.

Also known asPMAPhenylmercury acetateMercuric acetate phenylPhenylmercuric monoacetateAcetoxyphenylmercury
CAS Number62-38-4
AppearanceWhite to cream-colored crystalline powder or prisms. Practically odorless. Solid at room temperature.
Flash PointNot applicable (non-flammable solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid with negligible vapor pressure)
Water ReactivitySlightly soluble in water; no violent reaction but may slowly hydrolyze
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1674

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic heavy-metal contamination.

PPE Requirements

⚠️ Level B minimum with full-face SCBA; impervious gloves and suit required; prevent all skin contact due to absorption hazard

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; prevent skin contact and mercury-contaminated dust or runoff spread.

Isolation & Evacuation

ERG 151: isolate spill/leak area immediately for at least 25-50m in all directions; if large spill isolate 100m; evacuate downwind areas if airborne dust
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1674 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated liquid, powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 151, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1674 — Phenylmercuric acetate
HAZMAT RADIO NOTE — UN 1674 Product: Phenylmercuric acetate Class 6 / Toxic / ERG 151 PPE: Level B minimum with full-face SCBA; impervious gloves and suit required; prevent all skin contact due to absorption hazard ISOLATION: ERG 151: isolate spill/leak area immediately for at least 25-50m in all directions; if large spill isolate 100m; evacuate downwind areas if airborne dust ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1674 — Phenylmercuric acetate Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: White to cream-colored crystalline powder or prisms. Practically odorless. Solid at room temperature. Water Reactivity: Slightly soluble in water; no violent reaction but may slowly hydrolyze Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic heavy-metal contamination. PPE: Level B minimum with full-face SCBA; impervious gloves and suit required; prevent all skin contact due to absorption hazard Isolation: ERG 151: isolate spill/leak area immediately for at least 25-50m in all directions; if large spill isolate 100m; evacuate downwind areas if airborne dust — Key Hazards — • HIGHLY TOXIC mercury compound; may be harmful or fatal if inhaled, ingested or absorbed through skin. • Dust or solution can contaminate clothing, tools, equipment and runoff. • Fire or heating may produce toxic mercury fumes and irritating decomposition products. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/phenylmercuric-acetate-un-1674 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1674 Phenylmercuric acetate Cls6 ERG151 | allfirefighter.com/hazmat/un/phenylmercuric-acetate-un-1674SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/phenylmercuric-acetate-un-1674

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1674

UN 1674 is Phenylmercuric acetate, a hazardous material assigned to ERG Guide 151.

No. It is generally not flammable, but fire or heating can produce toxic mercury fumes.

ERG Guide 151 applies to UN 1674 for initial isolation, protective actions and first response guidance.

UN 1674 presents toxic mercury dust, ingestion, skin contact and contaminated-runoff hazards. Heating or fire may release mercury-containing fumes, and dry powder can contaminate clothing and equipment.

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; prevent skin contact and mercury-contaminated dust or runoff spread.

Mercury compounds can create persistent toxic contamination in water, soil, tools and protective clothing, so runoff and decon waste should be controlled.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.