☣️ UN 2567 • CLASS 6

UN 2567 — Sodium pentachlorophenate

Placard: Toxic. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Sodium pentachlorophenate is a toxic solid shipped as UN 2567. Dust exposure, skin contact and contaminated runoff are the main response concerns.

Hazard overview: Dust or solutions can injure by inhalation, ingestion or skin contact. Fire can produce toxic chlorinated fumes, and runoff can create a significant environmental hazard.

Response guidance: Avoid dust generation, isolate the area and contain runoff. Use water spray, dry chemical, CO2 or foam according to the fire conditions and SDS, while preventing contaminated water from spreading.

Firefighter training notes: Train crews on toxic dust control, decon and environmental containment. Avoid dry sweeping or actions that disperse powder.

Regulatory context: UN 2567 is transported as Sodium pentachlorophenate, Class 6 toxic material. Verify exact product and emergency information from shipping papers.

Storage & handling: Store closed and dry in a toxic-material area away from acids, oxidizers, heat and drains. Provide spill containment.

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UN 2567 Quick Details

UN 2567
Product name: Sodium pentachlorophenate
DOT Class: 6
Placard type: Toxic
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill 25m all directions; for large spill isolate 50m; if fire or water involved evacuate 800m downwind

Common Hazards of UN 2567

  • Sodium pentachlorophenate is toxic; inhalation, ingestion or skin contact can cause serious injury.
  • Dust and solutions may irritate or burn skin, eyes and respiratory tract.
  • Heating or fire may produce toxic and corrosive chlorinated fumes.
  • Runoff may be toxic, corrosive and highly harmful to waterways.
  • Water solutions can be alkaline and corrosive.
  • Containers may rupture when heated.
  • Dust generation increases inhalation and contamination risk.

Chemical Identity & Physical Properties

Sodium pentachlorophenate is typically a white to tan crystalline powder or granules with a slight phenolic odor.

Also known asSodium pentachlorophenoxidePentachlorophenol sodium saltNaPCPSodium PCPDowicide G
CAS Number131-52-2
AppearanceWhite to tan crystalline powder or granules. Slight phenolic odor. Solid at room temperature.
Flash PointNot applicable (non-flammable solid)
Boiling PointDecomposes before boiling
Vapor DensityNot applicable (solid)
Water ReactivitySoluble in water, forms corrosive alkaline solution
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2567

Extinguishing Media

Water spray, dry chemical, CO2, or foam may be used

PPE Requirements

⚠️ Level B minimum; SCBA required; full chemical protective clothing; prevent any skin contact due to toxic and corrosive nature

Use SCBA for dust, smoke or unknown atmospheres. Wear full chemical protective clothing, gloves, boots and eye/face protection.

Isolation & Evacuation

ERG 154: isolate spill 25m all directions; for large spill isolate 50m; if fire or water involved evacuate 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 2567 Incident

  • Call 911 and the emergency response number on the shipping papers.
  • Keep unauthorized personnel away and avoid raising dust.
  • Stay upwind, uphill and upstream of dust, smoke and runoff.
  • Avoid breathing dust or fumes; prevent skin and eye contact.
  • Do not touch damaged containers or spilled material without chemical-resistant PPE.
  • Ventilate confined spaces only with trained personnel, SCBA and monitoring.
  • Use ERG 154, SDS and shipping papers to confirm isolation, decon and environmental controls.
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📋 Copy & Share Field Card

UN 2567 — Sodium pentachlorophenate
HAZMAT RADIO NOTE — UN 2567 Product: Sodium pentachlorophenate Class 6 / Toxic / ERG 154 PPE: Level B minimum; SCBA required; full chemical protective clothing; prevent any skin contact due to toxic and corrosive nature ISOLATION: ERG 154: isolate spill 25m all directions; for large spill isolate 50m; if fire or water involved evacuate 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2567 — Sodium pentachlorophenate Class: 6 | Placard: Toxic | ERG Guide: 154 Appearance: White to tan crystalline powder or granules. Slight phenolic odor. Solid at room temperature. Water Reactivity: Soluble in water, forms corrosive alkaline solution Extinguishing: Water spray, dry chemical, CO2, or foam may be used PPE: Level B minimum; SCBA required; full chemical protective clothing; prevent any skin contact due to toxic and corrosive nature Isolation: ERG 154: isolate spill 25m all directions; for large spill isolate 50m; if fire or water involved evacuate 800m downwind — Key Hazards — • Sodium pentachlorophenate is toxic; inhalation, ingestion or skin contact can cause serious injury. • Dust and solutions may irritate or burn skin, eyes and respiratory tract. • Heating or fire may produce toxic and corrosive chlorinated fumes. — First Actions — • Call 911 and the emergency response number on the shipping papers. • Keep unauthorized personnel away and avoid raising dust. • Stay upwind, uphill and upstream of dust, smoke and runoff. • Avoid breathing dust or fumes; prevent skin and eye contact. SOURCE: allfirefighter.com/hazmat/un/sodium-pentachlorophenate-un-2567 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2567 Sodium pentachlorophenate Cls6 ERG154 | allfirefighter.com/hazmat/un/sodium-pentachlorophenate-un-2567SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/sodium-pentachlorophenate-un-2567

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2567

Toxic exposure from dust, ingestion, skin contact or contaminated solutions is the main concern.

Yes. Fire may produce toxic and corrosive chlorinated fumes.

The material is toxic and contaminated runoff can harm waterways.

Yes. Dust increases inhalation exposure and spreads contamination.

SCBA and full chemical protective clothing are needed for dust, smoke or spill response.

Use ERG 154 with the SDS and shipping papers.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.