☣️ UN 2858 • CLASS 4

UN 2858 — Zirconium, dry, coiled wire, finished metal sheets, strip

Placard: Flammable Solid. ERG Guide 170. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Zirconium, dry, coiled wire, finished metal sheets, strip requires dry, cautious hazmat handling because moisture, dust, or damaged packaging can change the incident quickly. Verify the exact product condition before applying water or moving containers.

Hazard overview: The key hazards for Zirconium, dry, coiled wire, finished metal sheets, strip are reactive fire behavior, toxic or corrosive fumes, and contaminated runoff. Fine particles, damaged devices, or wet material can be much more dangerous than intact product.

Response guidance: Isolate the release, keep water away from reactive material, remove ignition sources, and monitor for hydrogen or acid gases where relevant. Use dry sand, dry powder, lime, soda ash, or other compatible dry media only when appropriate to the exact material.

Firefighter training notes: Training should focus on moisture exclusion, dry extinguishing media, gas monitoring, and withdrawal distances for UN 2858.

Regulatory context: Verify the SDS, shipping papers, packaging condition, and ERG 170 before selecting water, neutralization, or cleanup tactics.

Storage & handling: Store dry and tightly closed, away from water, humidity, incompatible acids/bases, oxidizers, fuels, and ignition sources as specified by SDS.

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UN 2858 Quick Details

UN 2858
Product name: Zirconium, dry, coiled wire, finished metal sheets, strip
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 170 (check current ERG)
Initial isolation: ERG 170: Isolate spill or leak area immediately for at least 25-50 meters in all directions. If fire involved, isolate 800 meters in all directions and consider initial evacuation for 800 meters.

Common Hazards of UN 2858

  • Dry zirconium forms can ignite; dust or fines may react with water and release flammable hydrogen gas.
  • Contact can injure skin, eyes, and respiratory tissue; fumes may collect in low or confined areas.
  • Fire may produce toxic or irritating decomposition products.
  • Containers or devices may rupture when heated or contaminated.
  • Direct water, foam, or incompatible agents can worsen the incident for released reactive material.
  • Runoff can become corrosive or contaminated and should be contained.
  • Use SDS, shipping papers, and monitoring before selecting final tactics.

Chemical Identity & Physical Properties

Silvery-gray to grayish-black metallic solid. Odorless. Appears as coiled wire, finished sheets, or strip form

Also known asZirconium metalZirconium wireZirconium sheetZirconium stripZr metal
CAS Number7440-67-7
AppearanceSilvery-gray to grayish-black metallic solid. Odorless. Appears as coiled wire, finished sheets, or strip form.
Flash PointNot applicable (pyrophoric metal when finely divided)
Boiling Point4409C (7968F)
Vapor DensityNot applicable (solid metal)
Water ReactivityFinely divided forms react violently with water, releasing flammable hydrogen gas. Finished coils, sheets, and strips are less reactive but may still react under certain conditions.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2858

Extinguishing Media

Dry sand, dry chemical, soda ash. Do not use water, foam, or halogenated agents.

PPE Requirements

⚠️ Level B minimum for fire conditions; SCBA required. Protective gloves and clothing to prevent friction ignition.

Use SCBA with chemical- and heat-protective clothing. Specialist metal-fire or water-reactive tactics may be needed, and distance remains part of PPE.

Isolation & Evacuation

ERG 170: Isolate spill or leak area immediately for at least 25-50 meters in all directions. If fire involved, isolate 800 meters in all directions and consider initial evacuation for 800 meters.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 170).

First Actions for a UN 2858 Incident

  • Call 911 and the emergency response number shown on shipping papers or the SDS.
  • Keep unauthorized personnel away and isolate the area from ignition and moisture sources.
  • Stay upwind, uphill, and upstream; avoid low areas where corrosive fumes or hydrogen may collect.
  • Avoid breathing fumes and prevent all skin and eye contact with material or runoff.
  • Do not touch containers or residue without SCBA and chemical-resistant PPE.
  • Do not apply water directly to the material unless specialist guidance confirms it is safe.
  • Use ERG guidance, SDS, shipping papers, and monitoring for hydrogen, acid gases, and oxygen levels.
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📋 Copy & Share Field Card

UN 2858 — Zirconium, dry, coiled wire, finished me
HAZMAT RADIO NOTE — UN 2858 Product: Zirconium, dry, coiled wire, finished metal sheets, strip Class 4 / Flammable Solid / ERG 170 PPE: Level B minimum for fire conditions; SCBA required. Protective gloves and clothing to prevent friction ignition. ISOLATION: ERG 170: Isolate spill or leak area immediately for at least 25-50 meters in all directions. If fire involved, isolate 800 meters in all directions and consider initial evacuation for 800 meters. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2858 — Zirconium, dry, coiled wire, finished metal sheets, strip Class: 4 | Placard: Flammable Solid | ERG Guide: 170 Appearance: Silvery-gray to grayish-black metallic solid. Odorless. Appears as coiled wire, finished sheets, or strip form. Water Reactivity: Finely divided forms react violently with water, releasing flammable hydrogen gas. Finished coils, sheets, and strips are less reactive but may still react under certain conditions. Extinguishing: Dry sand, dry chemical, soda ash. Do not use water, foam, or halogenated agents. PPE: Level B minimum for fire conditions; SCBA required. Protective gloves and clothing to prevent friction ignition. Isolation: ERG 170: Isolate spill or leak area immediately for at least 25-50 meters in all directions. If fire involved, isolate 800 meters in all directions and consider initial evacuation for 800 meters. — Key Hazards — • Dry zirconium forms can ignite; dust or fines may react with water and release flammable hydrogen gas. • Contact can injure skin, eyes, and respiratory tissue; fumes may collect in low or confined areas. • Fire may produce toxic or irritating decomposition products. — First Actions — • Call 911 and the emergency response number shown on shipping papers or the SDS. • Keep unauthorized personnel away and isolate the area from ignition and moisture sources. • Stay upwind, uphill, and upstream; avoid low areas where corrosive fumes or hydrogen may collect. • Avoid breathing fumes and prevent all skin and eye contact with material or runoff. SOURCE: allfirefighter.com/hazmat/un/zirconium-dry-coiled-wire-un-2858 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2858 Zirconium, dry, coiled wire, finished metal sheets, strip Cls4 ERG170 | allfirefighter.com/hazmat/un/zirconium-dry-coiled-wire-un-2858SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/zirconium-dry-coiled-wire-un-2858

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2858

Yes or potentially, depending on condition and exact product; avoid direct water on released material until specialist guidance is confirmed.

Hydrogen, acid gases, corrosive fumes, or metal oxide fumes may be possible depending on the material.

Dry sand, dry powder, lime, soda ash, or compatible dry agents may be needed; verify with SDS and ERG guidance.

Monitoring helps confirm flammable gas, acid gas, oxygen level, and safe entry conditions.

SCBA with chemical-resistant and heat-protective clothing is required for release or fire conditions.

Avoid moisture, incompatible agents, friction, and unnecessary container movement.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.